Long-Cycling Sulfide-Based All-Solid-State Batteries Enabled by Electrochemo-Mechanically Stable Electrodes
© 2022 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 24 vom: 11. Juni, Seite e2200401 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article Li-metal anodes Si anodes all-solid-state batteries cell-level energy densities interface engineering |
| Zusammenfassung: | © 2022 Wiley-VCH GmbH. The anode plays a critical role relating to the energy density in all-solid-state lithium batteries (ASLBs). Silicon (Si) and lithium (Li) metal are two of the most attractive anodes because of their ultrahigh theoretical capacities. However, most investigations focus on Li metal, leaving the great potential of Si underrated. This work investigates the stability, processability, and cost of Si anodes in ASLBs and compares them with Li metal. Moreover, single-crystal LiNi0.8 Mn0.1 Co0.1 O2 is stabilized with lithium silicate (Li2 SiOx ) through a scalable sol-gel method. ASLBs with a cell-level energy density of 285 Wh kg-1 are obtained by sandwiching the Si anode, the thin sulfide solid-state electrolyte membrane, and the interface stabilized LiNi0.8 Mn0.1 Co0.1 O2 . The full cell delivers a high capacity of 145 mAh g-1 at C/3 and maintains stability for 1000 cycles. This work inspires commercialization of ASLBs on a large scale with exciting manufacturing lines for large-scale, safe, and economical energy storage |
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| Beschreibung: | Date Revised 16.06.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202200401 |