Boosting Energy Efficiency and Stability of Li-CO2 Batteries via Synergy between Ru Atom Clusters and Single-Atom Ru-N4 sites in the Electrocatalyst Cathode

Boosting Energy Efficiency and Stability of Li-CO2 Batteries via Synergy between Ru Atom Clusters and Single-Atom Ru-N4 sites in the Electrocatalyst Cathode

© 2022 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 17 vom: 27. Apr., Seite e2200559
1. Verfasser: Lin, Jiangfeng (VerfasserIn)
Weitere Verfasser: Ding, Jingnan, Wang, Haozhi, Yang, Xinyi, Zheng, Xuerong, Huang, Zechuan, Song, Wanqing, Ding, Jia, Han, Xiaopeng, Hu, Wenbin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Li-CO2 batteries atomic cluster catalysts carbon quantum dots electronic synergy single-atom catalysts
Beschreibung
Zusammenfassung:© 2022 Wiley-VCH GmbH.
The Li-CO2 battery is a novel strategy for CO2 capture and energy-storage applications. However, the sluggish CO2 reduction and evolution reactions cause large overpotential and poor cycling performance. Herein, a new catalyst containing well-defined ruthenium (Ru) atomic clusters (RuAC ) and single-atom Ru-N4 (RuSA ) composite sites on carbon nanobox substrate (RuAC+SA NCB) (NCB = nitrogen-doped carbon nanobox) is fabricated by utilizing the different complexation effects between the Ru cation and the amine group (NH2 ) on carbon quantum dots or nitrogen moieties on NCB. Systematic experimental and theoretical investigations demonstrate the vital role of electronic synergy between RuAC and Ru-N4 in improving the electrocatalytic activity toward the CO2 evolution reaction (CO2 ER) and CO2 reduction reaction (CO2 RR). The electronic properties of the Ru-N4 sites are essentially modulated by the adjacent RuAC species, which optimizes the interactions with key reaction intermediates thereby reducing the energy barriers in the rate-determining steps of the CO2 RR and CO2 ER. Remarkably, the RuAC+SA @NCB-based cell displays unprecedented overpotentials as low as 1.65 and 1.86 V at ultrahigh rates of 1 and 2 A g-1 , and twofold cycling lifespan than the baselines. The findings provide a novel strategy to construct catalysts with composite active sites comprising multiple atom assemblies for high-performance metal-CO2 batteries
Beschreibung:Date Revised 27.04.2022
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.202200559