UV-light-driven cadmium sulphide (CdS) nanocatalysts : synthesis, characterization, therapeutic and environmental applications; kinetics and thermodynamic study of photocatalytic degradation of Eosin B and Methyl Green dyes

Cadmium sulphide (CdS) nanoparticles (NPs) were synthesized through hydrothermal route and characterized by UV-Vis spectroscopy, X-ray diffraction (XRD), Energy dispersive X-ray analysis, Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy and Thermo gravimetric analysis (TGA...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 85(2022), 4 vom: 01. Feb., Seite 1040-1052
1. Verfasser: Ali, Sundas (VerfasserIn)
Weitere Verfasser: Akbar Jan, F, Ullah, Rahat, Wajidullah, Ullah, Naimat, Salman
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Cadmium Compounds Coloring Agents Sulfides cadmium sulfide 057EZR4Z7Q Methyl Green 82-94-0 Eosine I Bluish OMS4XQD1T0
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245 1 0 |a UV-light-driven cadmium sulphide (CdS) nanocatalysts  |b synthesis, characterization, therapeutic and environmental applications; kinetics and thermodynamic study of photocatalytic degradation of Eosin B and Methyl Green dyes 
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520 |a Cadmium sulphide (CdS) nanoparticles (NPs) were synthesized through hydrothermal route and characterized by UV-Vis spectroscopy, X-ray diffraction (XRD), Energy dispersive X-ray analysis, Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy and Thermo gravimetric analysis (TGA).The band gap of CdS nanoparticles was found to be 2.38 eV. CdS NPs are crystalline aggregates with hexagonal structure as shown by SEM and XRD analysis. TGA study revealed that the synthesized nanomaterials were very stable to temperature and only 6.54% total loss occurred during heating range (25 °C-600 °C).The CdS NPs were used for the first time against the degradation of Eosin B (EB) and Methyl green (MG) dyes in aqueous solution.The degradation of EB and MG over CdS nanocatalysts followed second order kinetics. The predicted activation energies for both the dyes' reactions were 61.1 kJ/mol and 32.11 kJ/mol, respectively. About 95% and 90% dye degradation was observed at the time interval of 160 minutes for EB and MG, respectively. High percent degradation of EB was observed at high pH (pH 0) while at low pH (pH 4) high percent degradation was found for MG dye. Maximum dye degradation was found at the optimal dose (0.03 g/L) of the catalyst and at low dye concentration. The rate of EB and MG dye degradation was found to increase with increase in temperature up to 45 °C. The recyclability study showed that CdS nanoparticles could be reused for the degradation of the given dyes. Good antibacterial activity against Staphylococcus aureus was shown by CdS NPs. From the biocompatibility it was confirmed that CdS NPS are bioincompatible compatible 
650 4 |a Journal Article 
650 7 |a Cadmium Compounds  |2 NLM 
650 7 |a Coloring Agents  |2 NLM 
650 7 |a Sulfides  |2 NLM 
650 7 |a cadmium sulfide  |2 NLM 
650 7 |a 057EZR4Z7Q  |2 NLM 
650 7 |a Methyl Green  |2 NLM 
650 7 |a 82-94-0  |2 NLM 
650 7 |a Eosine I Bluish  |2 NLM 
650 7 |a OMS4XQD1T0  |2 NLM 
700 1 |a Akbar Jan, F  |e verfasserin  |4 aut 
700 1 |a Ullah, Rahat  |e verfasserin  |4 aut 
700 0 |a Wajidullah  |e verfasserin  |4 aut 
700 1 |a Ullah, Naimat  |e verfasserin  |4 aut 
700 0 |a Salman  |e verfasserin  |4 aut 
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773 1 8 |g volume:85  |g year:2022  |g number:4  |g day:01  |g month:02  |g pages:1040-1052 
856 4 0 |u http://dx.doi.org/10.2166/wst.2021.637  |3 Volltext 
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