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231225s2022 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202200083
|2 doi
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|a pubmed24n1124.xml
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|a (DE-627)NLM337280584
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|a (NLM)35196412
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
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|a Lee, Ji Eun
|e verfasserin
|4 aut
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|a Universal Solution Synthesis of Sulfide Solid Electrolytes Using Alkahest for All-Solid-State Batteries
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|c 2022
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 21.04.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2022 Wiley-VCH GmbH.
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|a The wet-chemical processability of sulfide solid electrolytes (SEs) provides intriguing opportunities for all-solid-state batteries. Thus far, sulfide SEs are wet-prepared either from solid precursors suspended in solvents (suspension synthesis) or from homogeneous solutions using SEs (solution process) with restricted composition spaces. Here, a universal solution synthesis method for preparing sulfide SEs from precursors, not only Li2 S, P2 S5 , LiCl, and Na2 S, but also metal sulfides (e.g., GeS2 and SnS2 ), fully dissolved in an alkahest: a mixture solvent of 1,2-ethylenediamine (EDA) and 1,2-ethanedithiol (EDT) (or ethanethiol). Raman spectroscopy and theoretical calculations reveal that the exceptional dissolving power of EDA-EDT toward GeS2 is due to the nucleophilicity of the thiolate anions that is strong enough to dissociate the GeS bonds. Solution-synthesized Li10 GeP2 S12 , Li6 PS5 Cl, and Na11 Sn2 PS12 exhibit high ionic conductivities (0.74, 1.3, and 0.10 mS cm-1 at 30 °C, respectively), and their application for all-solid-state batteries is successfully demonstrated
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|a Journal Article
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|a all-solid-state batteries
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|a inorganic solid electrolytes
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|a solution syntheses
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|a sulfides
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|a wet-chemical methods
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|a Park, Kern-Ho
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kim, Jin Chul
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wi, Tae-Ung
|e verfasserin
|4 aut
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|a Ha, A Reum
|e verfasserin
|4 aut
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1 |
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|a Song, Yong Bae
|e verfasserin
|4 aut
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|a Oh, Dae Yang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Woo, Jehoon
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kweon, Seong Hyeon
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yeom, Su Jeong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Cho, Woosuk
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kim, KyungSu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lee, Hyun-Wook
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kwak, Sang Kyu
|e verfasserin
|4 aut
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| 700 |
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|a Jung, Yoon Seok
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 34(2022), 16 vom: 12. Apr., Seite e2200083
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:34
|g year:2022
|g number:16
|g day:12
|g month:04
|g pages:e2200083
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|u http://dx.doi.org/10.1002/adma.202200083
|3 Volltext
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