Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents
Recent research has highlighted the key role played by the electron affinity of the active metal-nitrene/imido oxidant as the driving force in nitrene additions to olefins to afford valuable aziridines. The present work showcases a library of Co(II) reagents that, unlike the previously examined Mn(I...
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Bibliographische Detailangaben
| Veröffentlicht in: | Organometallics. - 1998. - 40(2021), 12 vom: 04. Juni, Seite 1974-1996
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| 1. Verfasser: |
Kalra, Anshika
(VerfasserIn) |
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| Weitere Verfasser: |
Bagchi, Vivek,
Paraskevopoulou, Patrina,
Das, Purak,
Ai, Lin,
Sanakis, Yiannis,
Raptopoulos, Grigorios,
Mohapatra, Sudip,
Choudhury, Amitava,
Sun, Zhicheng,
Cundari, Thomas R,
Stavropoulos, Pericles |
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| Format: | Online-Aufsatz
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| Sprache: | English |
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| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Organometallics
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| Schlagworte: | Journal Article |
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