Interfacial Behavior of Giant Amphiphiles Composed of Azobenzene and Polyhedral Oligomeric Silsesquioxane
Giant amphiphiles containing azobenzene and polyhedral oligomeric silsesquioxane (POSS) units are synthesized by linking 4,4'-azodianiline (ADA) and POSS derivatives by stepwise amidation and further modification. The synthesized giant amphiphiles are photoresponsive and show trans-cis isomeriz...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 38(2022), 4 vom: 01. Feb., Seite 1611-1620 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2022
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Giant amphiphiles containing azobenzene and polyhedral oligomeric silsesquioxane (POSS) units are synthesized by linking 4,4'-azodianiline (ADA) and POSS derivatives by stepwise amidation and further modification. The synthesized giant amphiphiles are photoresponsive and show trans-cis isomerization under ultraviolet (UV) irradiation. These giant amphiphiles are spread on the air-water interface and compressed by the barrier without and under UV irradiation. By compression, the giant amphiphiles undergo a phase transition from gas (G), liquid expanded (LE), liquid condensed (LC), and solid (S) to a final collapse on the water surface. The giant amphiphiles are cis-isomer-rich under UV irradiation and are trans-isomer-rich without UV irradiation. The trans-isomers are straight-shaped, while the cis-isomers are bent, and hence, their phase transition behaviors on the water surface exhibit a distinct difference |
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| Beschreibung: | Date Revised 01.02.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.1c03111 |