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231225s2022 xx |||||o 00| ||eng c |
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|a 10.1002/mrc.5242
|2 doi
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|e rakwb
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|a eng
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|a Alkorta, Ibon
|e verfasserin
|4 aut
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|a The use of DOSY experiments to determine the solution structures of coinage metal pyrazolates
|b The case of {[3,5-(CF3 )2 Pz]Ag}3
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|c 2022
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 09.03.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2021 John Wiley & Sons, Ltd.
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|a A series of DOSY experiments have been carried out to determine the solution stoichiometry of silver(I) 3,5-bis (trifluoromethyl)pyrazolate species. This compound exists as a trimer in the solid state (n = 3) but in solutions of chlorinated solvents, the DOSY data suggest the presence of a mixture of solvent stabilized monomer (n = 1) and dimer (n = 2) in equilibrium. Different approximations have been used including the Stokes-Einstein and the Stokes-Einstein-Gierer-Wirtz equations. Some methodological problems are discussed
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|a Journal Article
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|a DOSY
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|a SEGWE
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|a Stokes-Einstein
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|a fractal dimension
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|a silver pyrazolates
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| 650 |
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|a stoichiometry
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|a Benito, María Teresa
|e verfasserin
|4 aut
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| 700 |
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|a Elguero, José
|e verfasserin
|4 aut
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| 700 |
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|a Doyagüez, Elisa García
|e verfasserin
|4 aut
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| 700 |
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|a Patterson, Monika R
|e verfasserin
|4 aut
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| 700 |
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|a Jimeno, María Luisa
|e verfasserin
|4 aut
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|a Dias, H V Rasika
|e verfasserin
|4 aut
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|a Reviriego, Felipe
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 60(2022), 4 vom: 01. Apr., Seite 442-451
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnns
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| 773 |
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|g volume:60
|g year:2022
|g number:4
|g day:01
|g month:04
|g pages:442-451
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|u http://dx.doi.org/10.1002/mrc.5242
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