Influence of speciation distribution and particle size on heavy metal leaching from MSWI fly ash

Copyright © 2021 Elsevier Ltd. All rights reserved.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 138(2022) vom: 01. Feb., Seite 318-327
1. Verfasser: Bernasconi, Davide (VerfasserIn)
Weitere Verfasser: Caviglia, Caterina, Destefanis, Enrico, Agostino, Angelo, Boero, Renato, Marinoni, Nicoletta, Bonadiman, Costanza, Pavese, Alessandro
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article Heavy metal leaching MSWI fly ash Particle size Speciation Coal Ash Metals, Heavy Particulate Matter Solid Waste Carbon 7440-44-0
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520 |a Fly ash from municipal solid waste incineration (MSWI-FA) contains leachable heavy metals. In the present study the correlations between heavy metal content, particle size, speciation distribution with respect to water leaching are investigated, using a combination of solid-state bulk analytical techniques, leaching treatments, sequential extractions and thermodynamic geochemical modelling. Among the analyzed heavy metals, Zn and Pb are the most abundant in any grain size class, followed by Cu, Cr, Cd and Ni, with concentration that tends to increase with a decrease of the grain size. The phase composition is constituted of salt (halite, sylvite, anhydrite and syngenite), which provide the main minerals regardless of the particle size class; calcite, quartz and gehlenite occur in comparatively lower amounts, while 50% wt is composed of amorphous fraction. Heavy metal leaching is strongly correlated to speciation distribution, and in particular to the fraction (F1) associated with salt, carbonate and weak surface sorption. Leaching from speciation due to surface complexation on Al/Fe (hydr)oxide becomes relevant at acidic regime. Particle size and heavy metal content, in turn, moderately correlate with leaching. The F1-speciation as a function of particle size does not exhibit a definite trend shared by all heavy metals under investigation. This suggests that i) differences in speciation distribution, rather than bare heavy metal content or particle size, govern leaching from MSWI-FA; ii) F1 can be regarded as a marker of the potential heavy metal leaching; iii) a comparatively modest efficiency in managing MSWI-FA is expected from grain size separation strategies 
650 4 |a Journal Article 
650 4 |a Heavy metal leaching 
650 4 |a MSWI fly ash 
650 4 |a Particle size 
650 4 |a Speciation 
650 7 |a Coal Ash  |2 NLM 
650 7 |a Metals, Heavy  |2 NLM 
650 7 |a Particulate Matter  |2 NLM 
650 7 |a Solid Waste  |2 NLM 
650 7 |a Carbon  |2 NLM 
650 7 |a 7440-44-0  |2 NLM 
700 1 |a Caviglia, Caterina  |e verfasserin  |4 aut 
700 1 |a Destefanis, Enrico  |e verfasserin  |4 aut 
700 1 |a Agostino, Angelo  |e verfasserin  |4 aut 
700 1 |a Boero, Renato  |e verfasserin  |4 aut 
700 1 |a Marinoni, Nicoletta  |e verfasserin  |4 aut 
700 1 |a Bonadiman, Costanza  |e verfasserin  |4 aut 
700 1 |a Pavese, Alessandro  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 138(2022) vom: 01. Feb., Seite 318-327  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnns 
773 1 8 |g volume:138  |g year:2022  |g day:01  |g month:02  |g pages:318-327 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2021.12.008  |3 Volltext 
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