Two-Dimensional Cellular Patterning on a Polymer Film Based on Interfacial Stiffness

The mechanical properties in the outermost region of a polymer film strongly affect various material functions. We here propose a novel and promising strategy for the two-dimensional regulation of the mechanical properties of a polymer film at the water interface based on an inkjet drawing of silica...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 37(2021), 51 vom: 28. Dez., Seite 14911-14919
1. Verfasser: Kawabata, Kento (VerfasserIn)
Weitere Verfasser: Totani, Masayasu, Kawaguchi, Daisuke, Matsuno, Hisao, Tanaka, Keiji
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Water 059QF0KO0R Polyhydroxyethyl Methacrylate 25249-16-5
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520 |a The mechanical properties in the outermost region of a polymer film strongly affect various material functions. We here propose a novel and promising strategy for the two-dimensional regulation of the mechanical properties of a polymer film at the water interface based on an inkjet drawing of silica nanoparticles (SNPs) underneath it. A film of poly(2-hydroxyethyl methacrylate) (PHEMA), which exhibits excellent bioinertness properties at the water interface, was well fabricated on a substrate with a pattern of SNPs. X-ray photoelectron spectroscopy and atomic force microscopy confirmed that the surface of the PHEMA film was flat and chemically homogeneous. However, the film surface was in-plane heterogeneous in stiffness due to the presence of the underlying SNP lines. It was also noted that NIH/3T3 fibroblast cells selectively adhered and formed aggregates on the areas under which an SNP line was drawn 
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650 4 |a Research Support, Non-U.S. Gov't 
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700 1 |a Totani, Masayasu  |e verfasserin  |4 aut 
700 1 |a Kawaguchi, Daisuke  |e verfasserin  |4 aut 
700 1 |a Matsuno, Hisao  |e verfasserin  |4 aut 
700 1 |a Tanaka, Keiji  |e verfasserin  |4 aut 
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