Electronic Structure Analysis and Reactivity of the Bimetallic Bis-Titanocene Vinylcarboxylate Complex, [(Cp2Ti)2(O2C3TMS2)]†

Multimetallic redox cooperativity features heavily in both bioinorganic and synthetic reactions. Here, the electronic structure of the bimetallic Ti/Ti complex 11, [(Cp2Ti)2(O2C3TMS2)] has been revisited with EPR, confirming a predominantly TiIII/TiIII electronic structure. Reactions of 11 with 2,6-...

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Détails bibliographiques
Publié dans:Polyhedron. - 1997. - 207(2021) vom: 01. Okt.
Auteur principal: Huh, Daniel N (Auteur)
Autres auteurs: Maity, Asim, Van Trieste, Gerard P, Schley, Nathan D, Powers, David C, Tonks, Ian A
Format: Article en ligne
Langue:English
Publié: 2021
Accès à la collection:Polyhedron
Sujets:Journal Article