Electronic Structure Analysis and Reactivity of the Bimetallic Bis-Titanocene Vinylcarboxylate Complex, [(Cp2Ti)2(O2C3TMS2)]†

Multimetallic redox cooperativity features heavily in both bioinorganic and synthetic reactions. Here, the electronic structure of the bimetallic Ti/Ti complex 11, [(Cp2Ti)2(O2C3TMS2)] has been revisited with EPR, confirming a predominantly TiIII/TiIII electronic structure. Reactions of 11 with 2,6-...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Polyhedron. - 1997. - 207(2021) vom: 01. Okt.
1. Verfasser: Huh, Daniel N (VerfasserIn)
Weitere Verfasser: Maity, Asim, Van Trieste, Gerard P, Schley, Nathan D, Powers, David C, Tonks, Ian A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Polyhedron
Schlagworte:Journal Article