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231225s2022 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202108114
|2 doi
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|a pubmed24n1111.xml
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|a (DE-627)NLM333509226
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|a (NLM)34813680
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
1 |
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|a Zhang, Yijie
|e verfasserin
|4 aut
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| 245 |
1 |
0 |
|a Defect-Free Metal-Organic Framework Membrane for Precise Ion/Solvent Separation toward Highly Stable Magnesium Metal Anode
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|c 2022
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 10.02.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2021 Wiley-VCH GmbH.
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|a Metallic magnesium batteries are promising candidates beyond lithium-ion batteries; however, a passive interfacial layer because of the electro-reduction of solvents on Mg surfaces usually leads to ultrahigh overpotential for the reversible Mg chemistry. Inspired by the excellent separation effect of permselective metal-organic framework (MOF) at angstrom scale, a large-area and defect-free MOF membrane directly on Mg surfaces is here constructed. In this process, the electrochemical deprotonation of ligand can be facilitated to afford the self-correcting of intercrystalline voids until a seamless membrane formed, which can eliminate nonselective intercrystalline diffusion of electrolyte and realize selective Mg2+ transport but precisely separate the solvent molecules from the MOF channels. Compared with the continuous solvent reduction on bare Mg anode, the as-constructed MOF membrane is demonstrated to significantly stabilize the Mg electrode via suppressing the permeation of solvents, hence contributing to a low-overpotential plating/stripping in conventional electrolytes. The concept is demonstrated that membrane separation can serve as solid-electrolyte interphase, which would be widely applicable to other energy-storage systems
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|a Journal Article
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4 |
|a Mg-ion batteries
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| 650 |
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4 |
|a electro-deposition
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| 650 |
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4 |
|a membrane separation
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| 650 |
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4 |
|a metal-organic frameworks
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| 650 |
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4 |
|a solid-electrolyte interphase
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| 700 |
1 |
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|a Li, Jiang
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhao, Wanyu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Dou, Huanglin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhao, Xiaoli
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Liu, Yuan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Bowen
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yang, Xiaowei
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 34(2022), 6 vom: 05. Feb., Seite e2108114
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
1 |
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|g volume:34
|g year:2022
|g number:6
|g day:05
|g month:02
|g pages:e2108114
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| 856 |
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|u http://dx.doi.org/10.1002/adma.202108114
|3 Volltext
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|d 34
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