Additive Manufacturing of Ti3 C2 -MXene-Functionalized Conductive Polymer Hydrogels for Electromagnetic-Interference Shielding

© 2021 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 5 vom: 01. Feb., Seite e2106253
1. Verfasser: Liu, Ji (VerfasserIn)
Weitere Verfasser: Mckeon, Lorcan, Garcia, James, Pinilla, Sergio, Barwich, Sebastian, Möbius, Matthias, Stamenov, Plamen, Coleman, Jonathan N, Nicolosi, Valeria
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article MXenes additive manufacturing electromagnetic-interference shielding hydrogels poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS)
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520 |a The ongoing miniaturization of devices and development of wireless and implantable technologies demand electromagnetic interference (EMI)-shielding materials with customizability. Additive manufacturing of conductive polymer hydrogels with favorable conductivity and biocompatibility can offer new opportunities for EMI-shielding applications. However, simultaneously achieving high conductivity, design freedom, and shape fidelity in 3D printing of conductive polymer hydrogels is still very challenging. Here, an aqueous Ti3 C2 -MXene-functionalized poly(3,4-ethylenedioxythiophene):polystyrene sulfonate ink is developed for extrusion printing to create 3D objects with arbitrary geometries, and a freeze-thawing protocol is proposed to transform the printed objects directly into highly conductive and robust hydrogels with high shape fidelity on both the macro- and microscale. The as-obtained hydrogel exhibits a high conductivity of 1525.8 S m-1 at water content up to 96.6 wt% and also satisfactory mechanical properties with flexibility, stretchability, and fatigue resistance. Furthermore, the use of the printed hydrogel for customizable EMI-shielding applications is demonstrated. The proposed easy-to-manufacture approach, along with the highlighted superior properties, expands the potential of conductive polymer hydrogels in future customizable applications and represents a real breakthrough from the current state of the art 
650 4 |a Journal Article 
650 4 |a MXenes 
650 4 |a additive manufacturing 
650 4 |a electromagnetic-interference shielding 
650 4 |a hydrogels 
650 4 |a poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) 
700 1 |a Mckeon, Lorcan  |e verfasserin  |4 aut 
700 1 |a Garcia, James  |e verfasserin  |4 aut 
700 1 |a Pinilla, Sergio  |e verfasserin  |4 aut 
700 1 |a Barwich, Sebastian  |e verfasserin  |4 aut 
700 1 |a Möbius, Matthias  |e verfasserin  |4 aut 
700 1 |a Stamenov, Plamen  |e verfasserin  |4 aut 
700 1 |a Coleman, Jonathan N  |e verfasserin  |4 aut 
700 1 |a Nicolosi, Valeria  |e verfasserin  |4 aut 
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773 1 8 |g volume:34  |g year:2022  |g number:5  |g day:01  |g month:02  |g pages:e2106253 
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