Atomic Visualization and Switching of Ferroelectric Order in β-In2 Se3 Films at the Single Layer Limit

© 2021 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 3 vom: 10. Jan., Seite e2106951
1. Verfasser: Zhang, Zhimo (VerfasserIn)
Weitere Verfasser: Nie, Jinhua, Zhang, Zhihao, Yuan, Yuan, Fu, Ying-Shuang, Zhang, Wenhao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D antiferroelectrics 2D ferroelectrics In2Se3 films ferroelectric switching scanning tunneling microscopy single layer
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520 |a 2D ferroelectrics have received wide interest due to the remarkable quantum states of emerging physics at reduced dimensionality, associated with their exotic properties in high-performance and nonvolatile functional devices. Here, by combing molecular beam epitaxy synthesis and scanning tunneling microscopy characterization, two metastable phases of layered In2 Se3 films: β'- and β*-In2 Se3 are reported, which develop different types of in-plane spontaneous polarizations, thus resulting in different striped morphologies. The anti-ferroelectric order in β'-In2 Se3 and ferroelectric order of β*-In2 Se3 are identified, respectively, down to the 2D limit by comprehensive investigations of structural and spectroscopic signatures, including the lattice distortion, the spatial profile of images, the formation of domain structure, and the electronic band-bending by polarization charges at edges. The ferroelectric switching between those two phases are further controlled via applying an electric field generated from the scanning tunneling microscopy tip in a reversible manner. The intriguing tunability between the (anti-)ferroelectric orders in the 2D limit provides a promising platform for studying the interplay between electronic structure and ferroelectricity in van der Waals materials, and promotes potential development of miniaturized transistors and memory devices based on electric polarizations 
650 4 |a Journal Article 
650 4 |a 2D antiferroelectrics 
650 4 |a 2D ferroelectrics 
650 4 |a In2Se3 films 
650 4 |a ferroelectric switching 
650 4 |a scanning tunneling microscopy 
650 4 |a single layer 
700 1 |a Nie, Jinhua  |e verfasserin  |4 aut 
700 1 |a Zhang, Zhihao  |e verfasserin  |4 aut 
700 1 |a Yuan, Yuan  |e verfasserin  |4 aut 
700 1 |a Fu, Ying-Shuang  |e verfasserin  |4 aut 
700 1 |a Zhang, Wenhao  |e verfasserin  |4 aut 
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773 1 8 |g volume:34  |g year:2022  |g number:3  |g day:10  |g month:01  |g pages:e2106951 
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