Theoretical and experimental approach of fuel gas and carbon black production from coal tar pitch by thermal plasma process

The processing of coal tar pitch (CTP) to produce clean fuel gas and carbon black (CB) is studied in a plasma reactor equipped with a direct-current plasma torch. The composition of the gas produced and energy costs were estimated theoretically for the CTP pyrolysis and gasification processes by two...

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Veröffentlicht in:Environmental technology. - 1993. - 44(2023), 10 vom: 15. Apr., Seite 1379-1391
1. Verfasser: Prado, E S P (VerfasserIn)
Weitere Verfasser: Miranda, F S, Marquesi, A R, Essiptchouk, A, Labat Amaral, G A, da Silva Sobrinho, A S, Petraconi, G, Baldan, M R
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2023
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Coal tar pitch Fuel Gas carbon black equilibrium calculation thermal plasma Plasma Gases Coal Tar 8007-45-2 Soot mehr... Gases Steam Hydrogen 7YNJ3PO35Z Oxygen S88TT14065
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520 |a The processing of coal tar pitch (CTP) to produce clean fuel gas and carbon black (CB) is studied in a plasma reactor equipped with a direct-current plasma torch. The composition of the gas produced and energy costs were estimated theoretically for the CTP pyrolysis and gasification processes by two oxidants, namely oxygen and water vapor. We have found that the main gaseous compounds obtained in the pyrolysis and gasification processes are hydrogen (H2), carbon monoxide (CO), and very often carbon dioxide (CO2). For the pyrolysis case, the mean value of the synthesis gas concentration reaches a major value of 98 vol.% (H2 - 81 vol.%, CO - 17. vol.%). However, only 23% of the initial CTP is transformed into gas phase at 1100 K and its content increases up to 37.4% at a temperature of 3000 K. For oxygen gasification, the syngas quantity is little less compared to the pyrolysis case and attains 96.6 vol.% (H2 - 26.5 vol.%, CO - 70.1 vol.%) for T > 1100 K. An intermediate syngas content for the water steam gasification is 97.8 vol.% (with H2 - 55.8 vol.% and CO - 42.0 vol.%). The CB produced was composed of well-defined spherical particles of 30-nm size. Furthermore, it is composed of carbon (98.2%), and followed by oxygen (1.8%) with a surface area of 97 m2 g-1. The thermal plasma system shows high efficiency in conversion of CTP into high-value-added products 
650 4 |a Journal Article 
650 4 |a Coal tar pitch 
650 4 |a Fuel Gas 
650 4 |a carbon black 
650 4 |a equilibrium calculation 
650 4 |a thermal plasma 
650 7 |a Plasma Gases  |2 NLM 
650 7 |a Coal Tar  |2 NLM 
650 7 |a 8007-45-2  |2 NLM 
650 7 |a Soot  |2 NLM 
650 7 |a Gases  |2 NLM 
650 7 |a Steam  |2 NLM 
650 7 |a Hydrogen  |2 NLM 
650 7 |a 7YNJ3PO35Z  |2 NLM 
650 7 |a Oxygen  |2 NLM 
650 7 |a S88TT14065  |2 NLM 
700 1 |a Miranda, F S  |e verfasserin  |4 aut 
700 1 |a Marquesi, A R  |e verfasserin  |4 aut 
700 1 |a Essiptchouk, A  |e verfasserin  |4 aut 
700 1 |a Labat Amaral, G A  |e verfasserin  |4 aut 
700 1 |a da Silva Sobrinho, A S  |e verfasserin  |4 aut 
700 1 |a Petraconi, G  |e verfasserin  |4 aut 
700 1 |a Baldan, M R  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Environmental technology  |d 1993  |g 44(2023), 10 vom: 15. Apr., Seite 1379-1391  |w (DE-627)NLM098202545  |x 1479-487X  |7 nnns 
773 1 8 |g volume:44  |g year:2023  |g number:10  |g day:15  |g month:04  |g pages:1379-1391 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2021.2003437  |3 Volltext 
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