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231225s2022 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202106465
|2 doi
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|a pubmed24n1106.xml
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|a (DE-627)NLM33192076X
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|a (NLM)34651356
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|a DE-627
|b ger
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|e rakwb
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|a eng
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|a Ravat, Prince
|e verfasserin
|4 aut
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| 245 |
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|a De Novo Synthesis of Free-Standing Flexible 2D Intercalated Nanofilm Uniform over Tens of cm2
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|c 2022
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 02.06.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2021 Wiley-VCH GmbH.
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|a Of a variety of intercalated materials, 2D intercalated systems have attracted much attention both as materials per se, and as a platform to study atoms and molecules confined among nanometric layers. High-precision fabrication of such structures has, however, been a difficult task using the conventional top-down and bottom-up approaches. The de novo synthesis of a 3-nm-thick nanofilm intercalating a hydrogen-bonded network between two layers of fullerene molecules is reported here. The two-layered film can be further laminated into a multiply film either in situ or by sequential lamination. The 3 nm film forms uniformly over an area of several tens of cm2 at an air/water interface and can be transferred to either flat or perforated substrates. A free-standing film in air prepared by transfer to a gold comb electrode shows proton conductivity up to 1.4 × 10-4 S cm-1 . Electron-dose-dependent reversible bending of a free-standing 6-nm-thick nanofilm hung in a vacuum is observed under electron beam irradiation
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|a Journal Article
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|a 2D material
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4 |
|a fullerene
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4 |
|a hydrogen-bonding network
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4 |
|a intercalated structure
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| 650 |
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4 |
|a proton conductivity
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| 650 |
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4 |
|a supramolecular polymerization
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| 650 |
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4 |
|a ultrathin film
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|a Uchida, Hikaru
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Sekine, Ryosuke
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kamei, Ko
|e verfasserin
|4 aut
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1 |
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|a Yamamoto, Akihisa
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Konovalov, Oleg
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Tanaka, Motomu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yamada, Teppei
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Harano, Koji
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Nakamura, Eiichi
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 34(2022), 22 vom: 25. Juni, Seite e2106465
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
1 |
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|g volume:34
|g year:2022
|g number:22
|g day:25
|g month:06
|g pages:e2106465
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|u http://dx.doi.org/10.1002/adma.202106465
|3 Volltext
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