The Quest for Stable Potassium-Ion Battery Chemistry

© 2021 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 34(2022), 5 vom: 04. Feb., Seite e2106876
1. Verfasser: Wu, Xianyong (VerfasserIn)
Weitere Verfasser: Qiu, Shen, Liu, Yao, Xu, Yunkai, Jian, Zelang, Yang, Jihui, Ji, Xiulei, Liu, Jun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article K2Mn[Fe(CN)6] Prussian white analogues electrodes electrolytes potassium-ion batteries
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520 |a Potassium-ion batteries (KIBs) have attracted wide interest for energy storage because of the abundance of the electrode materials involved; however, their electrochemical performances are far behind what can be achieved from lithium-ion batteries (LIBs) or sodium-ion batteries (SIBs). Herein, key promising electrode and electrolyte materials for potassium-ion batteries are identified, the coupled electrochemical reactions in the cell are investigated, and the compatibility between different materials is demonstrated to play the most important role. K2 Mn[Fe(CN)6 ] cathode can deliver a high capacity of ≈125 mAh g-1 and exceptional cycling stability over 61 000 cycles (≈9 months) if the side reactions from the anode can be prevented. Graphite is a good anode material but is subjected to degradation in traditional carbonate electrolytes. New concentrated electrolytes are developed and evaluated. A stable KIB system is demonstrated by coupling a stable K2 Mn[Fe(CN)6 ] cathode, a prepotassiated graphite anode with a concentrated electrolyte to achieve a high energy density of ≈260 Wh kg-1 (based on the active mass of cathode and anode) and good cycling of over 1000 cycles 
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650 4 |a K2Mn[Fe(CN)6] 
650 4 |a Prussian white analogues 
650 4 |a electrodes 
650 4 |a electrolytes 
650 4 |a potassium-ion batteries 
700 1 |a Qiu, Shen  |e verfasserin  |4 aut 
700 1 |a Liu, Yao  |e verfasserin  |4 aut 
700 1 |a Xu, Yunkai  |e verfasserin  |4 aut 
700 1 |a Jian, Zelang  |e verfasserin  |4 aut 
700 1 |a Yang, Jihui  |e verfasserin  |4 aut 
700 1 |a Ji, Xiulei  |e verfasserin  |4 aut 
700 1 |a Liu, Jun  |e verfasserin  |4 aut 
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