Dual-Single-Atom Tailoring with Bifunctional Integration for High-Performance CO2 Photoreduction
© 2021 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 49 vom: 01. Dez., Seite e2105135 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article CO2 photoreduction charge transfer conjugated carbon nitride polymers dimetal Co-Ru atoms selective CO2 adsorption synergistic photocatalysis |
| Zusammenfassung: | © 2021 Wiley-VCH GmbH. Single-atom photocatalysis has been demonstrated as a novel strategy to promote heterogeneous reactions. There is a diversity of monoatomic metal species with specific functions; however, integrating representative merits into dual-single-atoms and regulating cooperative photocatalysis remain a pressing challenge. For dual-single-atom catalysts, enhanced photocatalytic activity would be realized through integrating bifunctional properties and tuning the synergistic effect. Herein, dual-single-atoms supported on conjugated porous carbon nitride polymer are developed for effective photocatalytic CO2 reduction, featuring the function of cobalt (Co) and ruthenium (Ru). A series of in situ characterizations and theoretical calculations are conducted for quantitative analysis of structure-performance correlation. It is concluded that the active Co sites facilitate dynamic charge transfer, while the Ru sites promote selective CO2 surface-bound interaction during CO2 photoreduction. The combination of atom-specific traits and the synergy between Co and Ru lead to the high photocatalytic CO2 conversion with corresponding apparent quantum efficiency (AQE) of 2.8% at 385 nm, along with a high turnover number (TON) of more than 200 without addition of any sacrificial agent. This work presents an example of identifying the roles of different single-atom metals and regulating the synergy, where the two metals with unique properties collaborate to further boost the photocatalytic performance |
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| Beschreibung: | Date Revised 20.05.2022 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202105135 |