|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM331531402 |
| 003 |
DE-627 |
| 005 |
20231225213656.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2021 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202105248
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1105.xml
|
| 035 |
|
|
|a (DE-627)NLM331531402
|
| 035 |
|
|
|a (NLM)34611943
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Kim, Jeonghyeon
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Crystal Phase Transition Creates a Highly Active and Stable RuCX Nanosurface for Hydrogen Evolution Reaction in Alkaline Media
|
| 264 |
|
1 |
|c 2021
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 01.12.2021
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2021 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Although metastable crystal structures have received much attention owing to their utilization in various fields, their phase-transition to a thermodynamic structure has attracted comparably little interest. In the case of nanoscale crystals, such an exothermic phase-transition releases high energy within a confined surface area and reconstructs surface atomic arrangement in a short time. Thus, this high-energy nanosurface may create novel crystal structures when some elements are supplied. In this work, the creation of a ruthenium carbide (RuCX , X < 1) phase on the surface of the Ru nanocrystal is discovered during phase-transition from cubic-close-packed to hexagonal-close-packed structure. When the electrocatalytic hydrogen evolution reaction (HER) is tested in alkaline media, the RuCX exhibits a much lower overpotential and good stability relative to the counterpart Ru-based catalysts and the state-of-the-art Pt/C catalyst. Density functional theory calculations predict that the local heterogeneity of the outermost RuCX surface promotes the bifunctional HER mechanism by providing catalytic sites for both H adsorption and facile water dissociation
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a alkaline media
|
| 650 |
|
4 |
|a hydrogen evolution reaction
|
| 650 |
|
4 |
|a nanosurfaces
|
| 650 |
|
4 |
|a phase transitions
|
| 650 |
|
4 |
|a ruthenium carbide
|
| 700 |
1 |
|
|a Kim, Hee Jin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ruqia, Bibi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Kim, Mi Ji
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Jang, Yeong-Ji
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Jo, Tae Hwan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Baik, Hionsuck
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Oh, Hyung-Suk
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chung, Hee-Suk
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Baek, Kangkyun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Noh, Siwoo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Jung, Moonjung
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Kim, Ki-Jeong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lim, Hyung-Kyu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Youn, Young-Sang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Choi, Sang-Il
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 33(2021), 48 vom: 25. Dez., Seite e2105248
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:33
|g year:2021
|g number:48
|g day:25
|g month:12
|g pages:e2105248
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202105248
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 33
|j 2021
|e 48
|b 25
|c 12
|h e2105248
|