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231225s2022 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202105204
|2 doi
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|a pubmed24n1105.xml
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|a DE-627
|b ger
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Li, Yunxiang
|e verfasserin
|4 aut
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| 245 |
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|a Loading Single-Ni Atoms on Assembled Hollow N-Rich Carbon Plates for Efficient CO2 Electroreduction
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|c 2022
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 07.01.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2021 Wiley-VCH GmbH.
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|a The rational design of catalysts' spatial structure is vitally important to boost catalytic performance through exposing the active sites, enhancing the mass transfer, and confining the reactants. Herein, a dual-linker zeolitic tetrazolate framework-engaged strategy is developed to construct assembled hollow plates (AHP) of N-rich carbon (NC), which is loaded with single-Ni atoms to form a highly efficient electrocatalyst (designated as Ni-NC(AHP)). In the carbonization process, the thermally unstable linker (5-aminotetrazole) serves as the self-sacrificial template and the other linker (2-methylimidazole) mainly serves as the carbon and nitrogen source to form hollow NC matrix. The formed Ni-NC(AHP) catalyst possesses enhanced mesoporosity and more available surface area, thus promoting mass transport and affording abundant accessible single-Ni sites. These features contribute to remarkable performance for electrochemical CO2 reduction with exceptionally high selectivity of nearly 100% towards CO in a wide potential range and dramatically enhanced CO partial current density
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|a Journal Article
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|a CO2 reduction
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|a electrocatalysis
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|a hollow carbon
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|a single-atom catalysts
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1 |
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|a Zhang, Song Lin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Cheng, Weiren
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Chen, Ye
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Luan, Deyan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Gao, Shuyan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lou, Xiong Wen David
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 34(2022), 1 vom: 01. Jan., Seite e2105204
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:34
|g year:2022
|g number:1
|g day:01
|g month:01
|g pages:e2105204
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|u http://dx.doi.org/10.1002/adma.202105204
|3 Volltext
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