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231225s2021 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.1c01491
|2 doi
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|a pubmed24n1101.xml
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|a (DE-627)NLM330420909
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|a (NLM)34499835
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Xue, Shuwen
|e verfasserin
|4 aut
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|a Calcium-Modified Fe3O4 Nanoparticles Encapsulated in Humic Acid for the Efficient Removal of Heavy Metals from Wastewater
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|c 2021
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 23.09.2021
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|a Date Revised 07.12.2022
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Ca-modified Fe3O4 nanoparticles encapsulated in humic acid (HA-Ca/Fe3O4) were produced using a co-precipitation method. Furthermore, the adsorption performance of HA-Ca/Fe3O4 as well as the effect of coexisting ions and mechanisms were evaluated. A good description of the adsorption process was given using pseudo-second-order kinetic and Langmuir models. The adsorption capacities of HA-Ca/Fe3O4 for Pb2+, Cu2+, and Cd2+ were 208.33, 98.33, and 99.01 mg g-1, respectively. The 0.02-0.1 times concentrations in alkali and alkaline-earth metals promoted Pb2+ and Cd2+ adsorption; however, any concentration of alkali and alkaline-earth metals inhibited Cu2+-ion adsorption, probably owing to the differences in ionic radii between the interfering and heavy-metal ions. Pb2+, Cu2+, and Cd2+ removal using HA-Ca/Fe3O4 occurred via ion exchange, complexation of O-containing functional groups, mineral precipitation, and π-electron coordination. A method was proposed to calculate the contribution of these mechanisms to the adsorption process. In practice, HA-Ca/Fe3O4 can remove 99% Pb2+ and 91% Cu2+ and Cd2+ from real wastewater samples. Following five adsorption-desorption cycles, HA-Ca/Fe3O4 adsorption capacity did not change significantly. The aforementioned results indicated that HA-Ca/Fe3O4 presented a good potential in removing heavy metals in wastewater
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|a Journal Article
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|a Humic Substances
|2 NLM
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|a Metals, Heavy
|2 NLM
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|a Waste Water
|2 NLM
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|a Water Pollutants, Chemical
|2 NLM
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|a Calcium
|2 NLM
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|a SY7Q814VUP
|2 NLM
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|a Fan, Jinjin
|e verfasserin
|4 aut
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|a Wan, Keji
|e verfasserin
|4 aut
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|a Wang, Guoqiang
|e verfasserin
|4 aut
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|a Xiao, Yawen
|e verfasserin
|4 aut
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|a Bo, Wenting
|e verfasserin
|4 aut
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|a Gao, Mingqiang
|e verfasserin
|4 aut
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|a Miao, Zhenyong
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 37(2021), 37 vom: 21. Sept., Seite 10994-11007
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:37
|g year:2021
|g number:37
|g day:21
|g month:09
|g pages:10994-11007
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|u http://dx.doi.org/10.1021/acs.langmuir.1c01491
|3 Volltext
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|d 37
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|h 10994-11007
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