Calcium-Modified Fe3O4 Nanoparticles Encapsulated in Humic Acid for the Efficient Removal of Heavy Metals from Wastewater

Ca-modified Fe3O4 nanoparticles encapsulated in humic acid (HA-Ca/Fe3O4) were produced using a co-precipitation method. Furthermore, the adsorption performance of HA-Ca/Fe3O4 as well as the effect of coexisting ions and mechanisms were evaluated. A good description of the adsorption process was give...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 37(2021), 37 vom: 21. Sept., Seite 10994-11007
1. Verfasser: Xue, Shuwen (VerfasserIn)
Weitere Verfasser: Fan, Jinjin, Wan, Keji, Wang, Guoqiang, Xiao, Yawen, Bo, Wenting, Gao, Mingqiang, Miao, Zhenyong
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Humic Substances Metals, Heavy Waste Water Water Pollutants, Chemical Calcium SY7Q814VUP
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520 |a Ca-modified Fe3O4 nanoparticles encapsulated in humic acid (HA-Ca/Fe3O4) were produced using a co-precipitation method. Furthermore, the adsorption performance of HA-Ca/Fe3O4 as well as the effect of coexisting ions and mechanisms were evaluated. A good description of the adsorption process was given using pseudo-second-order kinetic and Langmuir models. The adsorption capacities of HA-Ca/Fe3O4 for Pb2+, Cu2+, and Cd2+ were 208.33, 98.33, and 99.01 mg g-1, respectively. The 0.02-0.1 times concentrations in alkali and alkaline-earth metals promoted Pb2+ and Cd2+ adsorption; however, any concentration of alkali and alkaline-earth metals inhibited Cu2+-ion adsorption, probably owing to the differences in ionic radii between the interfering and heavy-metal ions. Pb2+, Cu2+, and Cd2+ removal using HA-Ca/Fe3O4 occurred via ion exchange, complexation of O-containing functional groups, mineral precipitation, and π-electron coordination. A method was proposed to calculate the contribution of these mechanisms to the adsorption process. In practice, HA-Ca/Fe3O4 can remove 99% Pb2+ and 91% Cu2+ and Cd2+ from real wastewater samples. Following five adsorption-desorption cycles, HA-Ca/Fe3O4 adsorption capacity did not change significantly. The aforementioned results indicated that HA-Ca/Fe3O4 presented a good potential in removing heavy metals in wastewater 
650 4 |a Journal Article 
650 7 |a Humic Substances  |2 NLM 
650 7 |a Metals, Heavy  |2 NLM 
650 7 |a Waste Water  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a Calcium  |2 NLM 
650 7 |a SY7Q814VUP  |2 NLM 
700 1 |a Fan, Jinjin  |e verfasserin  |4 aut 
700 1 |a Wan, Keji  |e verfasserin  |4 aut 
700 1 |a Wang, Guoqiang  |e verfasserin  |4 aut 
700 1 |a Xiao, Yawen  |e verfasserin  |4 aut 
700 1 |a Bo, Wenting  |e verfasserin  |4 aut 
700 1 |a Gao, Mingqiang  |e verfasserin  |4 aut 
700 1 |a Miao, Zhenyong  |e verfasserin  |4 aut 
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773 1 8 |g volume:37  |g year:2021  |g number:37  |g day:21  |g month:09  |g pages:10994-11007 
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