Ultrathin PdAuBiTe Nanosheets as High-Performance Oxygen Reduction Catalysts for a Direct Methanol Fuel Cell Device
© 2021 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 42 vom: 15. Okt., Seite e2103383 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article 2D nanostructures Pd-based nanoalloys direct methanol fuel cell devices oxygen reduction reaction ultrathin nanosheets |
| Zusammenfassung: | © 2021 Wiley-VCH GmbH. Ultrathin 2D metal nanostructures have sparked a lot of research interest because of their improved electrocatalytic properties for fuel cells. So far, no effective technique for preparing ultrathin 2D Pd-based metal nanostructures with more than three compositions has been published. Herein, a new visible-light-induced template technique for producing PdAuBiTe alloyed 2D ultrathin nanosheets is developed. The mass activity of the PdAuBiTe nanosheets against the oxygen reduction reaction (ORR) is 2.48 A mgPd -1 , which is 27.5/17.7 times that of industrial Pd/C/Pt/C, respectively. After 10 000 potential cyclings, there is no decrease in ORR activity. The PdAuBiTe nanosheets exhibit high methanol tolerance and in situ anti-CO poisoning properties. The PdAuBiTe nanosheets, as cathode electrocatalysts in direct methanol fuel cells, can thus give significant improvement in terms of power density and durability. In O2 /air, the power density can be increased to 235.7/173.5 mW cm-2 , higher than that reported in previous work, and which is 2.32/3.59 times higher than Pt/C |
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| Beschreibung: | Date Revised 20.10.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202103383 |