A Pyrite Iron Disulfide Cathode with a Copper Current Collector for High-Energy Reversible Magnesium-Ion Storage
© 2021 Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 41 vom: 11. Okt., Seite e2103881 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article cathode materials copper current collectors iron disulfide magnesium-ion storage rechargeable magnesium batteries |
| Zusammenfassung: | © 2021 Wiley-VCH GmbH. Owing to its low cost, high theoretical capacity, and environmentally friendly characteristics, pyrite FeS2 demonstrates promise as a cathode material for high-energy metal-anode-based rechargeable batteries. When it is used in a rechargeable magnesium battery (RMB), the electrode couple exhibits an extremely low theoretical volume change upon full discharge. However, its electrochemical Mg-ion storage is considerably hindered by slow reaction kinetics. In this study, a high-performance FeS2 cathode for RMBs using a copper current collector is reported, which is involved in cathode reactions via a reversible redox process between copper and cuprous sulfide. This phase transformation with the formation of copper nanowires during discharge activates the redox reactions of FeS2 via a two-step and four-electron Mg-ion transfer that dominates the cathode reactions. As a result, the as-prepared FeS2 nanomaterial cathode delivers a significantly enhanced reversible capacity of 679 mAh g-1 at 50 mA g-1 . The corresponding energy density of 714 Wh kg-1 is superior to those of all previously reported metal chalcogenide cathodes in RMBs or hybrid batteries using a Mg metal anode. Notably, the as-assembled FeS2 -Mg battery can operate over 1000 cycles with a good capacity retention at 400 mA g-1 |
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| Beschreibung: | Date Revised 13.10.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202103881 |