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231225s2021 xx |||||o 00| ||eng c |
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|a 10.1021/acs.organomet.1c00041
|2 doi
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|a pubmed24n1099.xml
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|a eng
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| 100 |
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|a Romine, Andrew M
|e verfasserin
|4 aut
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|a Ligand Rearrangement Leads to Tetrahydrothiophene-Functionalized N,S-Heterocyclic Carbene Palladium(II) Complexes
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|c 2021
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 27.07.2022
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Tetrahydrothiophene-functionalized N,S-heterocyclic carbene palladium(II) complexes are synthesized through an unexpected rearrangement that proceeds with palladium(II) trifluoroacetate and not with palladium(II) acetate, palladium(II) bromide, or palladium(II) chloride. A series of these complexes were isolated and characterized by X-ray crystallography. The mechanism of formation of these [3.2.1]-palladabicycles was explored, and the catalytic capabilities of these complexes were demonstrated in representative C-C coupling reactions
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|a Journal Article
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|a Demer, Matthew J
|e verfasserin
|4 aut
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|a Gembicky, Milan
|e verfasserin
|4 aut
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|a Rheingold, Arnold L
|e verfasserin
|4 aut
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| 700 |
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|a Engle, Keary M
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Organometallics
|d 1998
|g 40(2021), 14 vom: 26. Juli, Seite 2311-2319
|w (DE-627)NLM098167103
|x 0276-7333
|7 nnns
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| 773 |
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|g volume:40
|g year:2021
|g number:14
|g day:26
|g month:07
|g pages:2311-2319
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|u http://dx.doi.org/10.1021/acs.organomet.1c00041
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