Exceptionally High Blocking Temperature of 17 K in a Surface-Supported Molecular Magnet

Exceptionally High Blocking Temperature of 17 K in a Surface-Supported Molecular Magnet

© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 40 vom: 24. Okt., Seite e2102844
1. Verfasser: Paschke, Fabian (VerfasserIn)
Weitere Verfasser: Birk, Tobias, Enenkel, Vivien, Liu, Fupin, Romankov, Vladyslav, Dreiser, Jan, Popov, Alexey A, Fonin, Mikhail
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article dimetallofullerenes electrospray deposition graphene relaxation single-molecule magnets
Beschreibung
Zusammenfassung:© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.
Single-molecule magnets (SMMs) are among the most promising building blocks for future magnetic data storage or quantum computing applications, owing to magnetic bistability and long magnetic relaxation times. The practical device integration requires realization of 2D surface assemblies of SMMs, where each magnetic unit shows magnetic relaxation being sufficiently slow at application-relevant temperatures. Using X-ray absorption spectroscopy and X-ray magnetic circular dichroism, it is shown that sub-monolayers of Dy2 C80 (CH2 Ph) dimetallofullerenes prepared on graphene by electrospray deposition exhibit magnetic behavior fully comparable to that of the bulk. Magnetic hysteresis and relaxation time measurements show that the magnetic moment remains stable for 100 s at 17 K, marking the blocking temperature TB(100) , being not only in excellent agreement with that of the bulk sample but also representing by far the highest one detected for a surface-supported single-molecule magnet. The reported findings give a boost to the efforts to stabilize and address the spin degree of freedom in molecular magnets aiming at the realization of SMM-based spintronic units
Beschreibung:Date Revised 13.10.2024
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.202102844