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231225s2021 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202102083
|2 doi
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|a pubmed25n1094.xml
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|a DE-627
|b ger
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Yu, Wei
|e verfasserin
|4 aut
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| 245 |
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|a Facile Production of Phosphorene Nanoribbons towards Application in Lithium Metal Battery
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|c 2021
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 02.09.2021
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2021 Wiley-VCH GmbH.
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|a Like phosphorene, phosphorene nanoribbon (PNR) promises exotic properties but unzipping phosphorene into edge-defined PNR is non-trivial because of uncontrolled cutting of phosphorene along random directions. Here a facile electrochemical strategy to fabricate zigzag-edged PNRs in high yield (>80%) is reported. The presence of chemically active zigzag edges in PNR allows it to spontaneously react with Li to form a Li+ ion conducting Li3 P phase, which can be used as a protective layer on Li metal anode in lithium metal batteries (LMBs). PNR protective layer prevents the parasitic reaction between lithium metal and electrolyte and promotes Li+ ion diffusion kinetics, enabling homogenous Li+ ion flux and long-time cycling stability up to 1100 h at a current density of 1 mA cm-2 . LiFePO4 |PNR-Li full-cell batteries with an areal capacity of 2 mAh cm-2 , a lean electrolyte (20 µl mAh-1 ) and a negative/positive (N/P) electrodes ratio of 3.5 can be stably cycled over 100 cycles
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|a Journal Article
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4 |
|a black phosphorous
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| 650 |
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4 |
|a electrochemical exfoliation
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| 650 |
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|a lithium metal batteries
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| 650 |
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4 |
|a lithium phosphide
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| 650 |
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4 |
|a phosphorene nanoribbons
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| 700 |
1 |
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|a Yang, Jinlin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Jing
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Kun
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Xu, Haomin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhou, Xin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Chen, Wei
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Loh, Kian Ping
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 33(2021), 35 vom: 24. Sept., Seite e2102083
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
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| 773 |
1 |
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|g volume:33
|g year:2021
|g number:35
|g day:24
|g month:09
|g pages:e2102083
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|u http://dx.doi.org/10.1002/adma.202102083
|3 Volltext
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