A COF-Like N-Rich Conjugated Microporous Polytriphenylamine Cathode with Pseudocapacitive Anion Storage Behavior for High-Energy Aqueous Zinc Dual-Ion Batteries
© 2021 Wiley-VCH GmbH.
| Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 34 vom: 20. Aug., Seite e2101857 |
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| Auteur principal: | |
| Autres auteurs: | , , , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2021
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| Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
| Sujets: | Journal Article aqueous zinc batteries conjugated microporous polymers high energy density polytriphenylamine pseudocapacitance |
| Résumé: | © 2021 Wiley-VCH GmbH. Conducting polymers with good electron conductivity and rich redox functional groups are promising cathode candidates for constructing high-energy aqueous zinc batteries. However, the glaring flaw of active-site underutilization impairs their electrochemical performance. Herein, we report a poriferous polytriphenylamine conjugated microporous polymer (CMP) cathode capable of accommodating Cl- anions in a pseudocapative-dominated manner for energy storage. Its specific 3D, covalent-organic-framework-like conjugated network ensures high accessibility efficacy of N active sites (up to 83.2% at 0.5 A g-1 ) and distinct physicochemical stability (87.6% capacity retention after 1000 cycles) during repeated charging/discharging courses. Such a robust CMP electrode also leads to a zinc dual-ion battery device with a high energy density of 236 W h kg-1 and a maximum power density of 6.8 kW kg-1 , substantially surpassing most recently reported organic-based zinc batteries. This study paves the way for the rational design of advanced CMP-based organic cathodes for high-energy devices |
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| Description: | Date Revised 25.08.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202101857 |