A Full-Spectrum Porphyrin-Fullerene D-A Supramolecular Photocatalyst with Giant Built-In Electric Field for Efficient Hydrogen Production
© 2021 Wiley-VCH GmbH.
| Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 31 vom: 01. Aug., Seite e2101026 |
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| Auteur principal: | |
| Autres auteurs: | , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2021
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| Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
| Sujets: | Journal Article TPPS/C60 charge separation donor-acceptor systems hydrogen production photocatalysis |
| Résumé: | © 2021 Wiley-VCH GmbH. A full-spectrum (300-850 nm) responsive donor-acceptor (D-A) supramolecular photocatalyst tetraphenylporphinesulfonate/fullerene (TPPS/C60 ) is successfully constructed. The theoretical spectral efficiency of TPPS/C60 is as high as 70%, offering the possibility of full-solar-spectrum light harvesting. The TPPS/C60 performs a highly efficient photocatalytic H2 evolution rate of 276.55 µmol h-1 (34.57 mmol g-1 h-1 ), surpassing many reported organic photocatalysts. The D-A structure effectively promotes electron transfer from TPPS to C60 , which is beneficial to the photocatalytic reaction. Specifically, a giant internal electric field in the D-A structure is built via the enhanced molecular dipole, which dramatically promotes the charge separation (CS) efficiency by 2.35 times. Transient absorption spectra results show a long-lived CS state TPPS•+ -C60 •- in the D-A structure, which effectively promotes participation of photogenerated electrons in the reduction reaction. Briefly, this work provides a novel approach for designing high-performance photocatalytic materials via enhancing the interfacial electric field |
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| Description: | Date Revised 05.08.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202101026 |