|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM327568593 |
| 003 |
DE-627 |
| 005 |
20231225201054.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2021 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.1c01035
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1091.xml
|
| 035 |
|
|
|a (DE-627)NLM327568593
|
| 035 |
|
|
|a (NLM)34210143
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Gan, Huihui
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Mechanically Strong and Electrochemically Stable Single-Ion Conducting Polymer Electrolytes Constructed from Hydrogen Bonding
|
| 264 |
|
1 |
|c 2021
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 13.07.2021
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Herein, composite membranes based on a single-ion conducting polymer electrolyte (SIPE) and poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) were prepared by an electrospinning technology. The SIPE with hydrogen bonding was obtained via reversible addition-fragmentation chain transfer (RAFT) copolymerization of 2-(3-(6-methyl-4-oxo-1,4-dihydropyrimidin-2-yl)ureido)ethyl methacrylate (UPyMA), poly(ethylene glycol) methyl ether methacrylate (PEGMA), and lithium 4-styrenesulfonyl (phenylsulfonyl) imide (SSPSILi). The obtained composite membrane exhibited a highly porous network structure, superior thermal stability (>300 °C), and high mechanical strength (17.3 MPa). The fabricated SIPE/PVDF-HFP composite membrane without lithium salts possessed a high ionic conductivity of 2.78 × 10-5 S cm-1 at 30 °C, excellent compatibility with the lithium metal electrode, and high lithium-ion transference number (0.89). The symmetric Li//Li cell exhibited a superior cycle performance without short circuit, indicating the generation of a stable interface between SIPE and the lithium metal electrode during the process of lithium plating/stripping, which could inhibit lithium dendrite growth in lithium metal batteries (LMBs). The Li//LiFePO4 cell also exhibited superior cycle life and excellent rate capability at 60 or 25 °C. In consequence, the composite membrane exhibits a considerable future prospect for advanced LMBs
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Li, Shaoqiao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Yong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yu, Liping
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Jirong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xue, Zhigang
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 37(2021), 27 vom: 13. Juli, Seite 8270-8280
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:37
|g year:2021
|g number:27
|g day:13
|g month:07
|g pages:8270-8280
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.1c01035
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 37
|j 2021
|e 27
|b 13
|c 07
|h 8270-8280
|