Construction of Supercapacitor-Based Ionic Diodes with Adjustable Bias Directions by Using Poly(ionic liquid) Electrolytes

© 2021 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 31 vom: 16. Aug., Seite e2100887
1. Verfasser: Feng, Jianze (VerfasserIn)
Weitere Verfasser: Wang, Yan, Xu, Yongtai, Ma, Hongyun, Wang, Gaowei, Ma, Pengjun, Tang, Yu, Yan, Xingbin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article diodes electrolytes ionic liquids rectification supercapacitors
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520 |a The newly emerging supercapacitor-diode (CAPode), integrating the characteristics of a diode into an electrical-double-layer capacitor, can be employed to extend conventional supercapacitors to new technological applications and may play a crucial role in grid stabilization, signal propagation, and logic operations. However, the reported CAPodes have only been able to realize charge storage in the positive-bias direction. Here, bias-direction-adjustable CAPodes realized by using a polycation-based ionic liquid (IL) or a polyanion-based IL as electrolyte in an asymmetric carbon-based supercapacitor architecture are proposed. The resulting CAPodes exhibit charge-storage function at only the positive- or negative-bias direction with a high rectification ratio (≈80% for rectification ratio II, RRII ) and an outstanding cycling life (4500 cycles), representing a crucial breakthrough for designing high-performance capacitive ionic diodes 
650 4 |a Journal Article 
650 4 |a diodes 
650 4 |a electrolytes 
650 4 |a ionic liquids 
650 4 |a rectification 
650 4 |a supercapacitors 
700 1 |a Wang, Yan  |e verfasserin  |4 aut 
700 1 |a Xu, Yongtai  |e verfasserin  |4 aut 
700 1 |a Ma, Hongyun  |e verfasserin  |4 aut 
700 1 |a Wang, Gaowei  |e verfasserin  |4 aut 
700 1 |a Ma, Pengjun  |e verfasserin  |4 aut 
700 1 |a Tang, Yu  |e verfasserin  |4 aut 
700 1 |a Yan, Xingbin  |e verfasserin  |4 aut 
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773 1 8 |g volume:33  |g year:2021  |g number:31  |g day:16  |g month:08  |g pages:e2100887 
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