Super Stretchable and Compressible Hydrogels Inspired by Hook-and-Loop Fasteners

Inspired by hook-and-loop fasteners, we designed a hydrogel network containing α-zirconium phosphate (ZrP) two-dimensional nanosheets with a high density of surface hydroxyl groups serving as nanopatches with numerous "hooks," while polymer chains with plentiful amine functional groups ser...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 37(2021), 25 vom: 29. Juni, Seite 7760-7770
1. Verfasser: Ding, Fuchuan (VerfasserIn)
Weitere Verfasser: Ding, Hao, Shen, Zhiqiang, Qian, Lei, Ouyang, Jun, Zeng, Songshan, Seery, Thomas A P, Li, Jiao, Wu, Guanzheng, Chavez, Sonia E, Smith, Andrew T, Liu, Lan, Li, Ying, Sun, Luyi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S. Hydrogels Polymers
LEADER 01000naa a22002652 4500
001 NLM326774459
003 DE-627
005 20231225195325.0
007 cr uuu---uuuuu
008 231225s2021 xx |||||o 00| ||eng c
024 7 |a 10.1021/acs.langmuir.1c00924  |2 doi 
028 5 2 |a pubmed24n1089.xml 
035 |a (DE-627)NLM326774459 
035 |a (NLM)34129778 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Ding, Fuchuan  |e verfasserin  |4 aut 
245 1 0 |a Super Stretchable and Compressible Hydrogels Inspired by Hook-and-Loop Fasteners 
264 1 |c 2021 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 05.07.2021 
500 |a Date Revised 05.07.2021 
500 |a published: Print-Electronic 
500 |a Citation Status MEDLINE 
520 |a Inspired by hook-and-loop fasteners, we designed a hydrogel network containing α-zirconium phosphate (ZrP) two-dimensional nanosheets with a high density of surface hydroxyl groups serving as nanopatches with numerous "hooks," while polymer chains with plentiful amine functional groups serve as "loops." Our multiscale molecular simulations confirm that both the high density of hydroxyl groups on nanosheets and the large number of amine functional groups on polymer chains are essential to achieve reversible interactions at the molecular scale, functioning as nano hook-and-loop fasteners to dissipate energy. As a result, the synthesized hydrogel possesses superior stretchability (>2100% strain), resilience to compression (>90% strain), and durability. Remarkably, the hydrogel can sustain >5000 cycles of compression with torsion in a solution mimicking synovial fluid, thus promising for potential biomedical applications such as artificial articular cartilage. This hook-and-loop model can be adopted and generalized to design a wide range of multifunctional materials with exceptional mechanical properties 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
650 7 |a Hydrogels  |2 NLM 
650 7 |a Polymers  |2 NLM 
700 1 |a Ding, Hao  |e verfasserin  |4 aut 
700 1 |a Shen, Zhiqiang  |e verfasserin  |4 aut 
700 1 |a Qian, Lei  |e verfasserin  |4 aut 
700 1 |a Ouyang, Jun  |e verfasserin  |4 aut 
700 1 |a Zeng, Songshan  |e verfasserin  |4 aut 
700 1 |a Seery, Thomas A P  |e verfasserin  |4 aut 
700 1 |a Li, Jiao  |e verfasserin  |4 aut 
700 1 |a Wu, Guanzheng  |e verfasserin  |4 aut 
700 1 |a Chavez, Sonia E  |e verfasserin  |4 aut 
700 1 |a Smith, Andrew T  |e verfasserin  |4 aut 
700 1 |a Liu, Lan  |e verfasserin  |4 aut 
700 1 |a Li, Ying  |e verfasserin  |4 aut 
700 1 |a Sun, Luyi  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 37(2021), 25 vom: 29. Juni, Seite 7760-7770  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:37  |g year:2021  |g number:25  |g day:29  |g month:06  |g pages:7760-7770 
856 4 0 |u http://dx.doi.org/10.1021/acs.langmuir.1c00924  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 37  |j 2021  |e 25  |b 29  |c 06  |h 7760-7770