Molecular View of the Distortion and Pinning Force of a Receding Contact Line : Impact of the Nanocavity Geometry
We present a molecular view using many-body dissipative particle dynamics simulations to unravel the pinning phenomenon of a liquid film receding over a solid substrate with a nanocavity. We find that the pinning force and distortion of the pinned contact line vary across different nanocavity shapes...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 37(2021), 23 vom: 15. Juni, Seite 7008-7018 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
|
| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | We present a molecular view using many-body dissipative particle dynamics simulations to unravel the pinning phenomenon of a liquid film receding over a solid substrate with a nanocavity. We find that the pinning force and distortion of the pinned contact line vary across different nanocavity shapes. We show that the mechanism of a caterpillar motion, which has previously been proposed for advancing precursor films, persists in a partially pinned receding contact line. Our results also demonstrate a localized clamping effect, which is originated from the variation of the dynamic contact angle along the pinned contact line. The simulation results suggest that the clamping effect can be controlled by the geometry of the nanocavity and hydrophilicity of the underlying substrate |
|---|---|
| Beschreibung: | Date Revised 15.06.2021 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.1c00599 |