Series of AzTO-Based Energetic Materials : Effect of Different π-π Stacking Modes on Their Thermal Stability and Sensitivity

π-Stacking is common in materials, but different π-π stacking modes remarkably affect the properties and performances of materials. In particular, weak interactions, π-stacking and hydrogen bonding, often have a great impact on the stability and sensitivity of high-energetic compounds. Therefore, se...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 37(2021), 23 vom: 15. Juni, Seite 7118-7126
1. Verfasser: Zhang, Jinhao (VerfasserIn)
Weitere Verfasser: Jin, Bo, Song, Yulan, Hao, Wenjia, Huang, Jiao, Guo, Jinkun, Huang, Tao, Guo, Zhicheng, Peng, Rufang
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a π-Stacking is common in materials, but different π-π stacking modes remarkably affect the properties and performances of materials. In particular, weak interactions, π-stacking and hydrogen bonding, often have a great impact on the stability and sensitivity of high-energetic compounds. Therefore, several of energetic materials based on 1,1'-dihydroxyazotetrazole (1) with a nearly flat structure, such as the salts of aminoguanidine (2), 1,3-diaminoguanidine (3), imidazole (4), pyrazole (5) and triaminoguanidine (6), and a cocrystal of 2-methylimidazole (7), were designed and synthesized. Based on single-crystal diffraction data, thermal decomposition behaviors, and the mechanical sensitivity test, the compounds of 4, 5, and 7 with face-to-face π-π stacking display outstanding thermal stability and insensitivity 
650 4 |a Journal Article 
700 1 |a Jin, Bo  |e verfasserin  |4 aut 
700 1 |a Song, Yulan  |e verfasserin  |4 aut 
700 1 |a Hao, Wenjia  |e verfasserin  |4 aut 
700 1 |a Huang, Jiao  |e verfasserin  |4 aut 
700 1 |a Guo, Jinkun  |e verfasserin  |4 aut 
700 1 |a Huang, Tao  |e verfasserin  |4 aut 
700 1 |a Guo, Zhicheng  |e verfasserin  |4 aut 
700 1 |a Peng, Rufang  |e verfasserin  |4 aut 
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