Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex

Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex

© 2021 The Authors. Published by American Chemical Society.

Bibliographische Detailangaben
Veröffentlicht in:Organometallics. - 1998. - 40(2021), 9 vom: 10. Mai, Seite 1213-1220
1. Verfasser: Kostera, Sylwia (VerfasserIn)
Weitere Verfasser: Weber, Stefan, Peruzzini, Maurizio, Veiros, Luis F, Kirchner, Karl, Gonsalvi, Luca
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Organometallics
Schlagworte:Journal Article
Beschreibung
Zusammenfassung:© 2021 The Authors. Published by American Chemical Society.
The catalytic reduction of carbon dioxide is a process of growing interest for the use of this simple and abundant molecule as a renewable building block in C1-chemical synthesis and for hydrogen storage. The well-defined, bench-stable alkylcarbonyl Mn(I) bis(phosphine) complex fac-[Mn(CH2CH2CH3)(dippe)(CO)3] [dippe = 1,2-bis(diisopropylphosphino)ethane] was tested as an efficient and selective non-precious-metal precatalyst for the hydrogenation of CO2 to formate under mild conditions (75 bar total pressure, 80 °C), in the presence of a Lewis acid co-catalyst (LiOTf) and a base (DBU). Mechanistic insight into the catalytic reaction is provided by means of density functional theory (DFT) calculations
Beschreibung:Date Revised 01.06.2021
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:0276-7333
DOI:10.1021/acs.organomet.0c00710