Direct Observation of the Relationship between Thixotropic Behavior and Shear-Induced Orientation of Clay Particles in Synesthetic Hectorite Suspensions

A thixotropic characteristics of aqueous gels containing smectite clay minerals were used in various industrial applications such as paint additives, which have been affected by the clay types and clay particle sizes. A model called a house-of-card arrangement of clay particles and anisotropic arran...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1999. - 37(2021), 21 vom: 01. Juni, Seite 6435-6441
1. Verfasser: Iwase, Hiroki (VerfasserIn)
Weitere Verfasser: Kubota, Munehiro, Itoh, Tetsuji, Ogura, Toshihiko, Ebina, Takeo, Ohtani, Hiroyuki, Kurosaka, Keiichi, Fukushima, Yoshiaki
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
LEADER 01000naa a22002652 4500
001 NLM325597162
003 DE-627
005 20231225192757.0
007 cr uuu---uuuuu
008 231225s2021 xx |||||o 00| ||eng c
024 7 |a 10.1021/acs.langmuir.1c00404  |2 doi 
028 5 2 |a pubmed24n1085.xml 
035 |a (DE-627)NLM325597162 
035 |a (NLM)34010001 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Iwase, Hiroki  |e verfasserin  |4 aut 
245 1 0 |a Direct Observation of the Relationship between Thixotropic Behavior and Shear-Induced Orientation of Clay Particles in Synesthetic Hectorite Suspensions 
264 1 |c 2021 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Revised 01.06.2021 
500 |a published: Print-Electronic 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a A thixotropic characteristics of aqueous gels containing smectite clay minerals were used in various industrial applications such as paint additives, which have been affected by the clay types and clay particle sizes. A model called a house-of-card arrangement of clay particles and anisotropic arrangement in aqueous gels has been proposed. We prepared different sizes of synthetic hectorite and studied them by scanning electron-assisted dielectric microscopy (SE-ADM) and simultaneous small-angle neutron scattering and rheological measurements (Rheo-SANS). The Rheo-SANS results indicated that the clay particles with the cross-sectional radius of 30 nm were clearly oriented in the direction of shear-flow (1 × 103 s-1) direction, but the anisotropic change was not observed for an aqueous gel with clays whose average radius was 19.5 nm. The present study suggested the thixotropic characteristics of aqueous gels depend on the hectorite particle size and aggregation structure under shear conditions 
650 4 |a Journal Article 
700 1 |a Kubota, Munehiro  |e verfasserin  |4 aut 
700 1 |a Itoh, Tetsuji  |e verfasserin  |4 aut 
700 1 |a Ogura, Toshihiko  |e verfasserin  |4 aut 
700 1 |a Ebina, Takeo  |e verfasserin  |4 aut 
700 1 |a Ohtani, Hiroyuki  |e verfasserin  |4 aut 
700 1 |a Kurosaka, Keiichi  |e verfasserin  |4 aut 
700 1 |a Fukushima, Yoshiaki  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1999  |g 37(2021), 21 vom: 01. Juni, Seite 6435-6441  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:37  |g year:2021  |g number:21  |g day:01  |g month:06  |g pages:6435-6441 
856 4 0 |u http://dx.doi.org/10.1021/acs.langmuir.1c00404  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 37  |j 2021  |e 21  |b 01  |c 06  |h 6435-6441