|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM325396191 |
| 003 |
DE-627 |
| 005 |
20231225192341.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2021 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202008631
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1084.xml
|
| 035 |
|
|
|a (DE-627)NLM325396191
|
| 035 |
|
|
|a (NLM)33988264
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Cao, Changsheng
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Divergent Paths, Same Goal
|b A Pair-Electrosynthesis Tactic for Cost-Efficient and Exclusive Formate Production by Metal-Organic-Framework-Derived 2D Electrocatalysts
|
| 264 |
|
1 |
|c 2021
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 22.06.2021
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2021 Wiley-VCH GmbH.
|
| 520 |
|
|
|a Electrosynthesis of formic acid/formate is a promising alternative protocol to industrial processes. Herein, a pioneering pair-electrosynthesis tactic is reported for exclusively producing formate via coupling selectively electrocatalytic methanol oxidation reaction (MOR) and CO2 reduction reaction (CO2 RR), in which the electrode derived from Ni-based metal-organic framework (Ni-MOF) nanosheet arrays (Ni-NF-Af), as well as the Bi-MOF-derived ultrathin bismuthenes (Bi-enes), both obtained through an in situ electrochemical conversion process, are used as efficient anodic and cathodic electrocatalysts, respectively, achieving concurrent yielding of the same high-value product at both electrodes with greatly reduced energy input. The as-prepared Ni-NF-Af only needs quite low potentials to reach large current densities (e.g., 100 mA cm-2 1.345 V) with ≈100% selectivity for anodic methanol-to-formate conversion. Meanwhile, for CO2 RR in the cathode, the as-prepared Bi-enes can simultaneously exhibit near-unity selectivity, large current densities, and good stability in a wide potential window toward formate production. Consequently, the coupled MOR//CO2 RR system based on the distinctive MOF-derived catalysts displays excellent performance for pair-electrosynthesis of formate, delivering high current densities and nearly 100% selectivity for formate production in both the anode and the cathode. This work provides a novel way to design advanced MOF-derived electrocatalysts and innovative electrolytic systems for electrochemical production of value-added feedstocks
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a CO2 reduction reaction
|
| 650 |
|
4 |
|a formic acid
|
| 650 |
|
4 |
|a metal-organic frameworks
|
| 650 |
|
4 |
|a methanol oxidation reaction
|
| 650 |
|
4 |
|a pair-electrosynthesis
|
| 700 |
1 |
|
|a Ma, Dong-Dong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Jia, Jingchun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xu, Qiang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Xin-Tao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhu, Qi-Long
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 33(2021), 25 vom: 02. Juni, Seite e2008631
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:33
|g year:2021
|g number:25
|g day:02
|g month:06
|g pages:e2008631
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202008631
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 33
|j 2021
|e 25
|b 02
|c 06
|h e2008631
|