|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM323447392 |
| 003 |
DE-627 |
| 005 |
20231225184215.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2021 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.1c00479
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1078.xml
|
| 035 |
|
|
|a (DE-627)NLM323447392
|
| 035 |
|
|
|a (NLM)33789046
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Divandari, Mohammad
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Applying an Oleophobic/Hydrophobic Fluorinated Polymer Monolayer Coating from Aqueous Solutions
|
| 264 |
|
1 |
|c 2021
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 13.04.2021
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Despite major advancements in the fabrication of low-surface-energy surfaces, the environmental consequences of their fabrication can be a serious issue, particularly in an industrial context. This is especially the case for fluorine-based coatings, which often require fluorinated solvents for their processing and applications. These solvents are not only detrimental to the ozone layer but also represent a potential workplace hazard because they tend to bioaccumulate. We describe the design, synthesis, and characterization of a new fluorinated-polymer coating that can be simply applied to surfaces from an aqueous environment using a dip-coating technique. This was made possible by copolymerizing three different methacrylate monomers, each serving a specific function. Namely, fluorinated methacrylate providing oleo/hydrophobicity, photocleavable polyethylene glycol (PEG) methacrylate promoting water solubility of the copolymer, and thioether-based methacrylate serving as an anchoring unit to a number of different substrates. This copolymer is initially grafted to the surface as a monolayer from an aqueous solvent, after which the system is treated with ultraviolet (UV) light, cleaving away the protecting PEG moieties to yield an oleo/hydrophobic surface
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Arcifa, Andrea
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ayer, Mathieu A
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Letondor, Christophe
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Spencer, Nicholas D
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 37(2021), 14 vom: 13. Apr., Seite 4387-4394
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:37
|g year:2021
|g number:14
|g day:13
|g month:04
|g pages:4387-4394
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.1c00479
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 37
|j 2021
|e 14
|b 13
|c 04
|h 4387-4394
|