Intercomparison Between Surrogate, Explicit, and Full Treatments of VSL Bromine Chemistry Within the CAM-Chem Chemistry-Climate Model
© 2020. The Authors.
| Veröffentlicht in: | Geophysical research letters. - 1984. - 48(2021), 4 vom: 28. Feb., Seite e2020GL091125 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Geophysical research letters |
| Schlagworte: | Journal Article CAM‐Chem CCMI lowermost stratospheric ozone tropospheric oxidation capacity very‐short lived bromine |
| Zusammenfassung: | © 2020. The Authors. Many Chemistry-Climate Models (CCMs) include a simplified treatment of brominated very short-lived (VSLBr) species by assuming CH3Br as a surrogate for VSLBr. However, neglecting a comprehensive treatment of VSLBr in CCMs may yield an unrealistic representation of the associated impacts. Here, we use the Community Atmospheric Model with Chemistry (CAM-Chem) CCM to quantify the tropospheric and stratospheric changes between various VSLBr chemical approaches with increasing degrees of complexity (i.e., surrogate, explicit, and full). Our CAM-Chem results highlight the improved accuracy achieved by considering a detailed treatment of VSLBr photochemistry, including sea-salt aerosol dehalogenation and heterogeneous recycling on ice-crystals. Differences between the full and surrogate schemes maximize in the lowermost stratosphere and midlatitude free troposphere, resulting in a latitudinally dependent reduction of ∼1-7 DU in total ozone column and a ∼5%-15% decrease of the OH/HO2 ratio. We encourage all CCMs to include a complete chemical treatment of VSLBr in the troposphere and stratosphere |
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| Beschreibung: | Date Revised 05.04.2025 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 0094-8276 |
| DOI: | 10.1029/2020GL091125 |