Adsorptive removal of direct red 80 and methylene blue from aqueous solution by potato peels : a comparison of anionic and cationic dyes

Adsorption of direct red 80 (DR 80) and methylene blue (MB) from aqueous solutions on potato peels (PP) has been compared. The use of peels in decontamination technology is very promising given the near zero-cost for the synthesis of those adsorbents. The selected potato peels were first analyzed by...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 83(2021), 6 vom: 15. März, Seite 1384-1398
1. Verfasser: Ben Jeddou, Khawla (VerfasserIn)
Weitere Verfasser: Bouaziz, Fatma, Ben Taheur, Fadia, Nouri-Ellouz, Oumèma, Ellouz-Ghorbel, Raoudha, Ellouz-Chaabouni, Semia
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Azo Compounds Coloring Agents Solutions Water Pollutants, Chemical C.I. direct red 80 1294D5G72N Methylene Blue T42P99266K
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245 1 0 |a Adsorptive removal of direct red 80 and methylene blue from aqueous solution by potato peels  |b a comparison of anionic and cationic dyes 
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520 |a Adsorption of direct red 80 (DR 80) and methylene blue (MB) from aqueous solutions on potato peels (PP) has been compared. The use of peels in decontamination technology is very promising given the near zero-cost for the synthesis of those adsorbents. The selected potato peels were first analyzed by scanning using electron microscopy (SEM) and Fourier transforms infrared spectroscopy (FTIR). Then the adsorption behavior was studied in a batch system. The adsorption process is affected by various parameters such as the solution pH (2-11), the initial concentration of the dye (20, 50, 100, 150 and 200 mg L-1), the adsorbent dose (0.1-3%), the temperature (303.16 K, 313.16 K, and 323.16 K), agitation (up to 250 rpm), as well as the contact time. Adsorption isotherms of the studied dye on the adsorbent were determined and compared with the Langmiur, Freundlich and Temkin adsorption models. The results show that the data was most similar to the Freundlich isotherm (R2 = 0.99). The maximum adsorption capacities (Qmax) of MB and DR 80 by the PP at temperatures 303.16 K, 313.16 K and 323.16 K were found to be approximately 97.08 mg g-1; 45.87 mg g-1; 61.35 mg g-1 and 27.778 mg g-1; 45.45 mg g-1; and 32.258 mg g-1. The kinetic data was compared to the pseudo-first-order, pseudo-second-order, and intraparticle diffusion models. This revealed that adsorption of methylene blue onto PP abided mostly to the pseudo-second-order kinetic model. Calculations of various thermodynamic parameters such as enthalpy change (ΔH), entropy change (ΔS), and free energy change (ΔG) display the endothermic and spontaneous nature of the adsorption process 
650 4 |a Journal Article 
650 7 |a Azo Compounds  |2 NLM 
650 7 |a Coloring Agents  |2 NLM 
650 7 |a Solutions  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a C.I. direct red 80  |2 NLM 
650 7 |a 1294D5G72N  |2 NLM 
650 7 |a Methylene Blue  |2 NLM 
650 7 |a T42P99266K  |2 NLM 
700 1 |a Bouaziz, Fatma  |e verfasserin  |4 aut 
700 1 |a Ben Taheur, Fadia  |e verfasserin  |4 aut 
700 1 |a Nouri-Ellouz, Oumèma  |e verfasserin  |4 aut 
700 1 |a Ellouz-Ghorbel, Raoudha  |e verfasserin  |4 aut 
700 1 |a Ellouz-Chaabouni, Semia  |e verfasserin  |4 aut 
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773 1 8 |g volume:83  |g year:2021  |g number:6  |g day:15  |g month:03  |g pages:1384-1398 
856 4 0 |u http://dx.doi.org/10.2166/wst.2021.075  |3 Volltext 
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