Decomposition of gaseous chlorobenzene using a DBD combined CuO/α-Fe2O3 catalysis system

Copper oxide and hematite (CuO/α-Fe2O3) composite catalysts were prepared by using goethite as precursor adopted impregnation way and applied to the dielectric barrier discharge (DBD) catalytic decomposition of gaseous chlorobenzene. The CuO/α-Fe2O3 composite was characterised by X-ray diffraction,...

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Publié dans:Environmental technology. - 1993. - 43(2022), 18 vom: 01. Juli, Seite 2743-2754
Auteur principal: Xie, Linxuan (Auteur)
Autres auteurs: Lu, Jun, Ye, Ganggui, Yao, Jieyu, Zou, Xuehua, Zhu, Chengzhu
Format: Article en ligne
Langue:English
Publié: 2022
Accès à la collection:Environmental technology
Sujets:Journal Article CuO Dielectric barrier discharge(DBD) chlorobenzene goethite α-Fe2O3
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520 |a Copper oxide and hematite (CuO/α-Fe2O3) composite catalysts were prepared by using goethite as precursor adopted impregnation way and applied to the dielectric barrier discharge (DBD) catalytic decomposition of gaseous chlorobenzene. The CuO/α-Fe2O3 composite was characterised by X-ray diffraction, Brunauer-Emmett-Teller method, scanning electron microscopy and X-ray photoelectron spectrometer technique. The decomposition efficiency and energy yield of gaseous chlorobenzene in DBD catalysis system were studied by a function of gas flow rate, initial concentration and input voltage. The results showed that the CuO/α-Fe2O3 composite catalyst exhibited remarkable performance on chlorobenzene decomposition when the molar ratio was 0.4 and calcination temperature was 450°C. When the chlorobenzene initial concentration was 230 mg m-3, the chlorobenzene decomposition efficiency and mineralisation rate on the DBD catalysis system reached 73.33% and 63.37%, respectively, its decomposition and mineralisation efficiency were enhanced about 20.5% and 16.61%, respectively, compared with the bare DBD system, and it also benefited to significantly reduce the ozone and NO2 by-products. The possible pathway of chlorobenzene decomposition in the DBD catalytic hybrid system was proposed based on the products analysis 
650 4 |a Journal Article 
650 4 |a CuO 
650 4 |a Dielectric barrier discharge(DBD) 
650 4 |a chlorobenzene 
650 4 |a goethite 
650 4 |a α-Fe2O3 
700 1 |a Lu, Jun  |e verfasserin  |4 aut 
700 1 |a Ye, Ganggui  |e verfasserin  |4 aut 
700 1 |a Yao, Jieyu  |e verfasserin  |4 aut 
700 1 |a Zou, Xuehua  |e verfasserin  |4 aut 
700 1 |a Zhu, Chengzhu  |e verfasserin  |4 aut 
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