In Situ Tracking of Wetting-Front Transient Heat Release on a Surface-Mounted Metal-Organic Framework
© 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 14 vom: 04. Apr., Seite e2006980 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2021
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article host-guest adsorption liquid imbibition metal-organic framework thin films sensor devices transient heat |
| Zusammenfassung: | © 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH. Transient heat generation during guest adsorption and host-guest interactions is a natural phenomenon in metal-organic framework (MOF) chemistry. However, in situ tracking of such MOF released heat is an insufficiently researched field due to the fast heat dissipation to the surroundings. Herein, a facile capillary-driven liquid-imbibition approach is developed for in situ tracking of transient heat release at the wetting front of surface-mounted MOFs (SURMOFs) on cellulosic fiber substrates. Spatiotemporal temperature distributions are obtained with infrared thermal imaging for a range of MOF-based substrates and imbibed liquids. Temperature rises at the wetting front of water and binary mixtures with organic solvents are found to be over 10 K with an ultrafast and distinguishable thermal signal response (<1 s) with a detectable concentration limit ≤1 wt%. As an advancement to the state-of-the-art in trace-solvent detection technologies, this study shows great prospects for the integration of SURMOFs in future sensor devices. Inspired by this prototypal study, SURMOF-based transient heat signal transduction is likely to be extended to an ever-expanding library of SURMOFs and other classes of surface-grafted porous materials, translating into a wide range of convenient, portable, and ubiquitous sensor devices |
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| Beschreibung: | Date Revised 13.10.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202006980 |