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231225s2021 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.0c03555
|2 doi
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|a pubmed24n1072.xml
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|a (NLM)33618516
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|a eng
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|a Tosco, Bruna
|e verfasserin
|4 aut
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|a Layer-by-Layer Naphthalenediimide/Zn Phosphonate Hybrid Films Grown from Aqueous Solutions by a Simple Deposition Technique
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|c 2021
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 23.02.2021
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Hybrid thin films containing N,N'-bis(2-phosphonoethyl)-1,4,5,8-naphthalenediimide (PNDI) and zinc cations (PNDI/Zn films) were built on silicon and indium tin oxide (ITO) substrates by a simple layer-by-layer deposition process. Silicon substrates primed with a layer of phosphonate groups were immersed alternately into zinc nitrate and PNDI aqueous solutions, yielding PNDI/Zn films containing up to 40 layers. ITO substrates, on the other hand, were used without priming, and the deposition sequence began with a PNDI layer. All film growth steps were conducted at room temperature, using aqueous solutions, thus assuring an environmentally clean process. The PNDI/Zn films were studied by X-ray reflectivity and grazing angle X-ray diffraction, using synchrotron radiation source. The films were constituted by crystallites, containing zinc phosphonate layers oriented nearly parallel to the substrate. PNDI/Zn films on ITO were reduced to stable free radicals, which were observed by UV-visible spectroscopy. Moreover, PNDI/Zn bulk materials with structural analogy with the films were produced
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|a Journal Article
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|a Melo, Barbra Poly-Anna Vera
|e verfasserin
|4 aut
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|a Hermida Merino, Daniel
|e verfasserin
|4 aut
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|a Rey, José Fernando Queiruga
|e verfasserin
|4 aut
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|a Brochsztain, Sergio
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 37(2021), 7 vom: 23. Feb., Seite 2494-2502
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:37
|g year:2021
|g number:7
|g day:23
|g month:02
|g pages:2494-2502
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|u http://dx.doi.org/10.1021/acs.langmuir.0c03555
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