Surface Termination of Solution-Processed CH3NH3PbI3 Perovskite Film Examined using Electron Spectroscopies

© 2020 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 3 vom: 17. Jan., Seite e2004981
1. Verfasser: Mirzehmet, Abduheber (VerfasserIn)
Weitere Verfasser: Ohtsuka, Tomoki, Abd Rahman, Syed A, Yuyama, Tomoki, Krüger, Peter, Yoshida, Hiroyuki
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article electron spectroscopy energy level alignment perovskite solar cell surface termination
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520 |a The interfaces of a perovskite solar cell significantly influence the charge processes in the cell, which contributes to the device performance with direct implication for surface potential, electronic structure, and chemical reactivity. The properties of the interface are strongly affected by the surface termination. In this work, the combination of ultraviolet photoelectron spectroscopy (UPS) and metastable-atom electron spectroscopy is demonstrated, to examine the surface termination of a solution-processed CH3NH3PbI3 perovskite film. The results show that the surface of the CH3NH3PbI3 perovskite film is terminated with a layer consisting of CH3NH3 and I. The interface energy level alignment for both occupied and unoccupied levels between CH3NH3PbI3 and C60 is also examined using UPS and low-energy inverse photoelectron spectroscopy. It turns out that an ideal energy level alignment is established for the electron collection and hole block at the perovskite and C60 interface 
650 4 |a Journal Article 
650 4 |a electron spectroscopy 
650 4 |a energy level alignment 
650 4 |a perovskite solar cell 
650 4 |a surface termination 
700 1 |a Ohtsuka, Tomoki  |e verfasserin  |4 aut 
700 1 |a Abd Rahman, Syed A  |e verfasserin  |4 aut 
700 1 |a Yuyama, Tomoki  |e verfasserin  |4 aut 
700 1 |a Krüger, Peter  |e verfasserin  |4 aut 
700 1 |a Yoshida, Hiroyuki  |e verfasserin  |4 aut 
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