Multi-Yolk-Shell MnOCarbon Nanopomegranates with Internal Buffer Space as a Lithium Ion Battery Anode

Multi-yolk-shell MnOmesoporous carbon (MnO@m-carbon) nanopomegranates, featuring MnO nanoparticles within cavities of m-carbon with internal space between the MnO nanoparticle and a cavity carbon shell, were subtly constructed. Moreover, the buffer space was well controlled by means of regulating th...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 37(2021), 6 vom: 16. Feb., Seite 2195-2204
1. Verfasser: Liu, Yingwei (VerfasserIn)
Weitere Verfasser: Sun, Siwei, Han, Jie, Gao, Cong, Fan, Lei, Guo, Rong
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Multi-yolk-shell MnOmesoporous carbon (MnO@m-carbon) nanopomegranates, featuring MnO nanoparticles within cavities of m-carbon with internal space between the MnO nanoparticle and a cavity carbon shell, were subtly constructed. Moreover, the buffer space was well controlled by means of regulating the size of the cavity in m-carbon or the content of MnO. The results of electrochemical measurements demonstrated that MnO(10)@m-carbon(22) nanopomegranates (MnO nanoparticle, 15 nm; cavity size, 22 nm) had the best cycling and rate performance for lithium ion storage. The pomegranate-like MnO@m-carbon nanostructures have shown several advantages for their excellent performance: the nanocavity in m-carbon can restrict the growth and agglomeration of MnO nanoparticles; the well-interconnected mesoporous carbon matrix provides a "highway" for electrons and lithium ion transport; the voids between the MnO nanoparticle and cavity shell can alleviate the volume expansion 
650 4 |a Journal Article 
700 1 |a Sun, Siwei  |e verfasserin  |4 aut 
700 1 |a Han, Jie  |e verfasserin  |4 aut 
700 1 |a Gao, Cong  |e verfasserin  |4 aut 
700 1 |a Fan, Lei  |e verfasserin  |4 aut 
700 1 |a Guo, Rong  |e verfasserin  |4 aut 
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