Development of 19 F-detected 1,1-ADEQUATE for the characterization of polyfluorinated and perfluorinated compounds

Development of 19 F-detected 1,1-ADEQUATE for the characterization of polyfluorinated and perfluorinated compounds

© 2021 John Wiley & Sons, Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Magnetic resonance in chemistry : MRC. - 1985. - 59(2021), 6 vom: 30. Juni, Seite 628-640
1. Verfasser: Raab, Jeffrey (VerfasserIn)
Weitere Verfasser: Pelmus, Marius, Buevich, Alexei V, Reibarkh, Mikhail, Tischenko, Evgeny, Frey, Michael, Williamson, R Thomas, Crouch, Ronald C, Martin, Gary E
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Magnetic resonance in chemistry : MRC
Schlagworte:Journal Article 19F-detected 1,1-ADEQUATE 1JCC DFT calculations INADEQUATE nJCC perfluoro polyfluoro
Beschreibung
Zusammenfassung:© 2021 John Wiley & Sons, Ltd.
Polyfluorinated and perfluorinated compounds in the environment are a growing health concern. 19 F-detected variants of commonly employed heteronuclear shift correlation experiments such as heteronuclear single quantum correlation (HSQC) and heteronuclear multiple bond correlation (HMBC) are available; 19 F-detected experiments that employ carbon-carbon homonuclear coupling, in contrast, have never been reported. Herein, we report the measurement of the 1 JCC and n JCC coupling constants of a simple perfluorinated phthalonitrile and the first demonstration of a 19 F-detected 1,1-ADEQUATE experiment
Beschreibung:Date Completed 24.05.2021
Date Revised 24.05.2021
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1097-458X
DOI:10.1002/mrc.5134