Controlled Synthesis of V-Doped Heterogeneous Ni3S2/NiS Nanorod Arrays as Efficient Hydrogen Evolution Electrocatalysts

The development of low-cost and high-efficient electrocatalysts toward hydrogen evolution reaction (HER) is highly desirable and challenging. Herein, the novel V-doped Ni3S2/NiS heterostructure nanorod arrays grown on nickel foam (VNS/NF-WM) are synthesized via a facile methanol-assisted hydrotherma...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 37(2021), 1 vom: 12. Jan., Seite 357-365
1. Verfasser: Yang, Dan (VerfasserIn)
Weitere Verfasser: Cao, Liyun, Feng, Liangliang, Huang, Jianfeng, Feng, Yongqiang, Liu, Qianqian, He, Danyang, Wang, Jun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Controlled Synthesis of V-Doped Heterogeneous Ni3S2/NiS Nanorod Arrays as Efficient Hydrogen Evolution Electrocatalysts 
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520 |a The development of low-cost and high-efficient electrocatalysts toward hydrogen evolution reaction (HER) is highly desirable and challenging. Herein, the novel V-doped Ni3S2/NiS heterostructure nanorod arrays grown on nickel foam (VNS/NF-WM) are synthesized via a facile methanol-assisted hydrothermal method. We demonstrate that the morphology, phase composition, and crystallinity of VNS/NF are well modulated by tuning the ratios of water/methanol solvent. The optimized VNS/NF-WM-heterostructured nanorod (volume ratio of water/methanol is 3:1) exhibits superior HER electrocatalytic activity with low overpotentials of 85 and 218 mV to yield current density values of 10 and 100 mA cm-2, respectively, meanwhile sustaining an excellent stability with almost an unchanged current density of 10 mA cm-2 for 60 h. Our work offers fresh insights into the rational design of highly active and stable earth-abundant-heterostructured electrocatalysts for the hydrogen fuel production 
650 4 |a Journal Article 
700 1 |a Cao, Liyun  |e verfasserin  |4 aut 
700 1 |a Feng, Liangliang  |e verfasserin  |4 aut 
700 1 |a Huang, Jianfeng  |e verfasserin  |4 aut 
700 1 |a Feng, Yongqiang  |e verfasserin  |4 aut 
700 1 |a Liu, Qianqian  |e verfasserin  |4 aut 
700 1 |a He, Danyang  |e verfasserin  |4 aut 
700 1 |a Wang, Jun  |e verfasserin  |4 aut 
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