Highly efficient oxidative-alkaline-leaching process of vanadium-chromium reducing residue and parameters optimization by response surface methodology

Vanadium-chromium reducing residue was not only a typical solid waste in the steel industry but also a valuable secondary source for recovery of vanadium and chromium. A highly efficient oxidative-alkaline-leaching technology with Na2S2O8 was applied in this work. The effect of experimental factors...

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Veröffentlicht in:Environmental technology. - 1993. - 43(2022), 14 vom: 01. Juni, Seite 2167-2176
1. Verfasser: Peng, Hao (VerfasserIn)
Weitere Verfasser: Shang, Qian, Chen, Ronghua, Zhang, Liuying, Chen, Ya, Guo, Jing
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2022
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Oxidative-alkaline-leaching response surface methodology vanadium Solid Waste Vanadium 00J9J9XKDE Chromium 0R0008Q3JB Sodium Hydroxide 55X04QC32I
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520 |a Vanadium-chromium reducing residue was not only a typical solid waste in the steel industry but also a valuable secondary source for recovery of vanadium and chromium. A highly efficient oxidative-alkaline-leaching technology with Na2S2O8 was applied in this work. The effect of experimental factors including m(NaOH)/m(Residue), liquid-to-solid ratio, reaction temperature, m(Na2S2O8)/m(Residue) and reaction time, on the leaching process were investigated. It was showed that 96.3% vanadium was leached out under selected conditions: m(NaOH)/m(Residue) = 0.30, liquid-to-solid ratio of 5 mL/g, reaction time of 60 min, m(Na2S2O8)/m(Residue) = 0.50, reaction temperature of 90°C and stirring rate at 500 rpm, respectively. The leaching kinetics behaviour analysis demonstrated that the controlling step of the reaction was the diffusion of residue through the liquid film, and the Ea for vanadium leaching out was calculated to 15.57 kJ/mol. Response surface methodology was applied to analyze the interaction of the main conditions and the results showed that the influence of experimental factors on the leaching efficiency of vanadium followed the order: m(NaOH)/m(Residue) (B) > m(Na2S2O8)/m(Residue) (C) > reaction temperature (E) > reaction time (D) > liquid-to-solid ratio (A) 
650 4 |a Journal Article 
650 4 |a Oxidative-alkaline-leaching 
650 4 |a response surface methodology 
650 4 |a vanadium 
650 7 |a Solid Waste  |2 NLM 
650 7 |a Vanadium  |2 NLM 
650 7 |a 00J9J9XKDE  |2 NLM 
650 7 |a Chromium  |2 NLM 
650 7 |a 0R0008Q3JB  |2 NLM 
650 7 |a Sodium Hydroxide  |2 NLM 
650 7 |a 55X04QC32I  |2 NLM 
700 1 |a Shang, Qian  |e verfasserin  |4 aut 
700 1 |a Chen, Ronghua  |e verfasserin  |4 aut 
700 1 |a Zhang, Liuying  |e verfasserin  |4 aut 
700 1 |a Chen, Ya  |e verfasserin  |4 aut 
700 1 |a Guo, Jing  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Environmental technology  |d 1993  |g 43(2022), 14 vom: 01. Juni, Seite 2167-2176  |w (DE-627)NLM098202545  |x 1479-487X  |7 nnas 
773 1 8 |g volume:43  |g year:2022  |g number:14  |g day:01  |g month:06  |g pages:2167-2176 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2020.1869317  |3 Volltext 
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