Tunable Photocontrolled Motions of Anil-Poly(ethylene terephthalate) Systems through Excited-State Intramolecular Proton Transfer and Trans-Cis Isomerization

© 2020 Wiley-VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 33(2021), 5 vom: 15. Feb., Seite e2005249
1. Verfasser: Huang, Arui (VerfasserIn)
Weitere Verfasser: Hu, Jie, Han, Mengmeng, Wang, Kangwei, Xia, Jian Long, Song, Jiajia, Fu, Xuelian, Chang, Kai, Deng, Xiaocong, Liu, Siwei, Li, Qianqian, Li, Zhen
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2021
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article anil excited-state intramolecular proton transfer (ESIPT) soft actuators trans-cis isomerization
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520 |a With the combination of excited-state intramolecular proton transfer and trans-cis isomerization as microscopic molecular motions under light stimulus, multiple photodeformable processes are achieved in anil-poly(ethylene terephthalate) systems, including simple bending, dancing butterflies, and switches. The doping films can realize light-driven contraction as large as 70% and bending angle of about 141°, upon a simple stretching process. The internal mechanism is confirmed by transient absorption spectra, and the relationship between molecular structure and photocontrolled motion is investigated by theoretical calculations and crystal analysis. This work provides a convenient approach by utilizing anils to fabricate reversible actuations with desirable geometries, greatly contributing to the applications and manufacturing of soft robots and related research 
650 4 |a Journal Article 
650 4 |a anil 
650 4 |a excited-state intramolecular proton transfer (ESIPT) 
650 4 |a soft actuators 
650 4 |a trans-cis isomerization 
700 1 |a Hu, Jie  |e verfasserin  |4 aut 
700 1 |a Han, Mengmeng  |e verfasserin  |4 aut 
700 1 |a Wang, Kangwei  |e verfasserin  |4 aut 
700 1 |a Xia, Jian Long  |e verfasserin  |4 aut 
700 1 |a Song, Jiajia  |e verfasserin  |4 aut 
700 1 |a Fu, Xuelian  |e verfasserin  |4 aut 
700 1 |a Chang, Kai  |e verfasserin  |4 aut 
700 1 |a Deng, Xiaocong  |e verfasserin  |4 aut 
700 1 |a Liu, Siwei  |e verfasserin  |4 aut 
700 1 |a Li, Qianqian  |e verfasserin  |4 aut 
700 1 |a Li, Zhen  |e verfasserin  |4 aut 
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