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231225s2021 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.0c03179
|2 doi
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|a pubmed24n1063.xml
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|a (DE-627)NLM319119378
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|a (NLM)33347292
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|a DE-627
|b ger
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Lyu, Xiaolin
|e verfasserin
|4 aut
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| 245 |
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|a Tailored Polymer Particles with Ordered Network Structures in Emulsion Droplets
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|c 2021
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 12.01.2021
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The structural control of block copolymer (BCP) particles, which determines their properties and utilities, is quite important. Understanding the structural relationship between solution-cast samples and polymer particles in a confined space is necessary to precisely regulate the internal structure of polymer particles. Therefore, a facile method by choosing an appropriate selective solvent is reported to prepare spherical polymer particles with ordered network structures. The rod-coil BCP, poly(dimethylsiloxane)-b-poly{2,5-bis[(4-methoxyphenyl)-oxycarbonyl]styrene} (PDMS-b-PMPCS), was chosen as a model polymer because of its strong phase segregation ability. First, the structures of the BCP with a thermodynamically stable lamellar structure cast from different selective solvents were systematically studied. Then, a polymer particle with the same internal structure as that of the solution-cast sample can be easily prepared by self-assembling in an emulsion confined space. The relatively large particle size is of importance in this process because the large value of the particle size to periodicity ratio can provide a weak confined environment. This method helps us understand the inherent self-assembling mechanism of polymer particles in an emulsion confined space and accurately control the internal structure of the polymer particle obtained
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|a Journal Article
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1 |
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|a Tang, Zhehao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Yujie
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Xiao, Anqi
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Shen, Zhihao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zheng, Shijun
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Fan, Xing-He
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 37(2021), 1 vom: 12. Jan., Seite 509-515
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:37
|g year:2021
|g number:1
|g day:12
|g month:01
|g pages:509-515
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|u http://dx.doi.org/10.1021/acs.langmuir.0c03179
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