Preparation and characterization of activated carbon developed from cotton cloth residue activated with phosphoric acid : adsorption of clofibric acid
Cotton cloth waste was used as a precursor to prepare activated carbon (ACCs) chemically activated with phosphoric acid. Adsorption behavior of prepared ACCs was correlated with physicochemical proprieties. The pore volume and BET surface of ACCs were determined by nitrogen adsorption isotherms and...
Veröffentlicht in: | Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 82(2020), 11 vom: 20. Dez., Seite 2513-2524 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2020
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Zugriff auf das übergeordnete Werk: | Water science and technology : a journal of the International Association on Water Pollution Research |
Schlagworte: | Journal Article Phosphoric Acids Water Pollutants, Chemical Charcoal 16291-96-6 Clofibric Acid 53PF01Q249 phosphoric acid E4GA8884NN |
Zusammenfassung: | Cotton cloth waste was used as a precursor to prepare activated carbon (ACCs) chemically activated with phosphoric acid. Adsorption behavior of prepared ACCs was correlated with physicochemical proprieties. The pore volume and BET surface of ACCs were determined by nitrogen adsorption isotherms and scanning electron microscopy was used to observe their surface morphologies. Fourier transform infrared (FTIR) spectroscopy analysis and pH point zero charge (pHPZC) were conducted to determine chemical properties. Under the optimal conditions: 50% impregnation ratio and thermal treatment under N2 flow at 600 °C during 60 min, the activated carbon prepared exhibits a high surface area 1,150 m2/g, 0.501 cm3/g micropore volume and an excellent adsorption performance. The adsorbed amount of clofibric acid is found to be 9.98 and 83 mg/g at, respectively, initial CA concentration of 10 and 100 mg/L at pH 3.0 and 20 °C. Diffusion and chemisorption are the steps controlling the adsorption of CA onto ACC 50% and the equilibrium data were well described by Freundlich isotherm |
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Beschreibung: | Date Completed 22.12.2020 Date Revised 22.12.2020 published: Print Citation Status MEDLINE |
ISSN: | 0273-1223 |
DOI: | 10.2166/wst.2020.524 |